Ionic liquids chemistry

Viewed in conjunction with the solid-like, nonvolatile nature of ionic liquids, it is apparent that TSILs can be thought of as liquid versions of solid-supported reagents. Unlike solid-supported reagents, however, TSILs possess the added advantages of kinetic mobility of the grafted functionality and an enormous operational surface area (Figure 2.3-1). It is this combination of features that makes TSILs an aspect of ionic liquids chemistry that is poised for explosive growth. 

Green chemistry aims to design the hazards out of chemical products and processes, including solvents. With ionic liquids, you do not have the same concerns as you have with, for example, volatile organic solvents, which can contribute to air pollution. Ionic liquid chemistry is a very new area that is not only extremely interesting from a fundamental chemistry point of view, but could also have a very large impact on industry. 

Considering the many different applications of NMR spectroscopy in ionic liquids, it has become clear that this method is ready for the whole range of studies related to ionic liquid chemistry. These days, NMR in ILs is not exotic anymore but a routine technique for everyday chemistry. Virtually all standard and advanced NMR experiments can be run in ionic liquids very much like in ordinary conventional solvents. 

It was our intention to provide in the nine previous chapters the essential information for a modern understanding of the nature of ionic liquids as well as a review of aU different synthetic applications that have benefited from ionic liquid technology so far. In the last five years - since the first edition of this book appeared - the field of ionic liquid chemistry has advanced greatly. Much insight has been added, many new promising applications have appeared but also some of the paradigms have had to be modified. 

Warner, I.M., El-Zahab, B., Siraj, N. Perspectives on moving ionic liquid chemistry into the solid phase. Anal. Chem. 86, 7184—7191 (2014)... 

Chang, J. K., M. T. Lee, W. T. Tsai, M. J. Deng, and I. W. Sun. 2009. X-ray photoelectron spectroscopy and in situ X-ray absorption spectroscopy studies on reversible insertion/desertion of dicyanamide anions into/from manganese oxide in ionic liquid. Chemistry of Materials 21 2688-2695. 

Silveira ET, Umpierre AP, Rossi LM, Machado G, Morais J, Soares GV, Baumvol DR, Texeira SR, Finchtner PFP, Dupont J (2004) The partial hydrogenation of benzene to cyclohexene by nanoscale ruthenium catalysts in imidazolium ionic liquids. Chemistry 10 3734-3740... 

Zhao S-F, Lu J-X, Bond AM, Zhang J (2012) Remarkable sensitivity of the electrochemical reduction of benzophenone to proton availability in ionic liquids. Chemistry 18(17) 5290-5301. doi 10.1002/chem.201103365... 

Apart from their continued use as counter-anions in the isolation of novel structures, interest in the anions [ECI4I , E = Al or Ga, in ionic liquid chemistry is waning, primarily because of the... 

Migowski, P. Dupont, J. (2007). Catalytic applications of metal nanoparticles in imidazolium ionic liquids. Chemistry A European Journal, Vol.l3, No.l, (November 2006), pp. 32-39, ISSN 1521-3765... 

The partial hydrogenation of benzene to cyclohexene by nanoscale ruthenium catalysts in imidazolium ionic liquids. Chemistry-A European Journal, 10, 3734-40. 

Pernak, J. Syguda, A Mirska, I. Pernak, A. Nawrot, J. Pradzynska, A. Griffin, S. T. Rogers, R. D. (2007). Choline derivative-based ionic liquids. Chemistry - A European Journal, 13(24), 6817-6827. 

Zech, O. KeUermeier, M. Thomaier, S. Maurer, E. Klein, R. Schreiner, C. Kunz, W. (2009 a). Alkali metal ohgoether carboxylates - a new class of ionic liquids. Chemistry - A European Jourrud, 15(6), 1341-1345. 

Self-assembled structure in room-temperature ionic liquids. Chemistry-a... 

Nakashima, T. and Kimizuka, N. (2002). Vesicles in salt Formation of bilayer membranes from dialkyldimethylammonium bromides in ether-containing ionic liquids. Chemistry Letters, 10,1018-1019. 

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