Iodine oxide fluorides

Perhaps the most reactive compound of the group is BiFs- It reacts extremely vigorously with H2O to form O3, OF2 and a voluminous brown precipitate which is probably a hydrated bismuth(V) oxide fluoride. At room temperature BiFs reacts vigorously with iodine or sulfur above 50° it converts paraffin oil to fluorocarbons at 150° it fluorinates UF4 to UF and at 180° it converts Brs to BrFs and BrFs, and CI2 to CIF. 

It is not hydrolysed by water but reacts quantitatively with NaOH to yield sodium perchlorate and fluoride. It oxidizes iodides to iodine. Perchloryl fluoride reacts with ammonia to yield ammonium perchlorylamide NH4NHCIO3 [45a]. It reacts with potassium and caesium hydroxide to yield crystalline precipitates of K2NCIO3 and CS2NCIO3. It is isomorphous with metal sulphates, is explosive and very sensitive to flame, shock and friction. 

Unfortunately, the absence of X-ray structural information and magnetic evidence has prevented the establishment of the formula Xe+[PtFe] for the 1 1 adduct, although the derivation of rubidium hexafluoroplatinate(V) from this compound in the oxidatively and reductively neutral solvent iodine penta-fluoride indicates that it is a hexafluoroplatinate(V). Some support for the... 

TELLURIUM (13494-80-9) Finely divided powder or dust may be flammable and explosive. Violent reaction with strong oxidizers, bromine pentafluoride, halogens, interhalogens, iodine pentafluoride, hexalithium disilicide, lithium silicide, nitrosyl fluoride, oxygen difluoride, sodium peroxide, sulfur, zinc. Incompatible with cadmium, cesium, hafnium, strong bases, chemically active metals, iodic acid, iodine oxide, lead chlorite, lead oxide, mercury oxides, nitric acid, peroxyformic acid, platinum, silver bromate/iodate/ fluoride, nitryl fluoride, sodium nitrate. 

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