Iodine anion name

On the basis of all these results and his own investigations on chloro- and bromo-de-diazoniations (Galli, 1981), Galli proposed in 1988 that iodo-de-diazoniation, after formation of the aryl radical in the initiation reaction (Scheme 10-22) follows three coupled iodination chain reactions based on the formation of the I2 molecule and the If anion in the step shown in Scheme 10-23, namely iodine atom (I ) addition (Scheme 10-24), and iodine abstraction from I2 and If in Schemes 10-25 and 10-26 respectively. Aryl radicals and iodine molecules are regenerated as indicated in Scheme 10-27. The addition of iodide ion to aryl radicals forming the radical anion [Arl] -, as in Scheme 10-28, is considered an unlikely pathway, as that reaction has been found to be reversible (Lawless and Hawley, 1969 Andrieux et al. 1979). 

Iodine is produced by similar methods, namely, oxidation of the iodide anion from brines by chlorine. However, iodine is also produced in a reductive process by reacting NalOs, extracted from the natural source of Chilean saltpeter, with sodium hydrogen snffite. The pentavalent iodine is reduced to iodide (equations), which is then treated and oxidized with a sufficient amonnt of the mother liquor to liberate elemental iodine (equation 5). In contrast to chlorine and bromine, which have large industrial uses, iodine has no predominant commercial use. 

Wieland, 1907 Wieland and Wecker, 1910). Oxidation was carried out in an inert solvent such as benzene, from which the salt precipitated. The easier and more reliable preparation of perchlorate salts by the iodine-silver perchlorate method (Weitz and Schwechten, 1926, 1927), to which we have referred earlier (p. 168), allowed a much clearer understanding of the nature of triarylaminium ions to be obtained. Isolation of perchlorates permitted chemical studies, and easy reduction to the triarylamine by iodide ion, ferrous ion, etc., was consistent with the cation-radical view that was developed. The name aminium ion was coined by Weitz. Other salts were prepared such as tritolylaminium picrate (by oxidation of the amine with lead dioxide in the presence of picric acid), and it was also recognized that conjugate anions in salts obtained by oxidation with antimony pentachloride, phosphorus pentachloride and ferric chloride had to be complex anions rather than simple anionic radicals. This is a particularly pertinent point in antimony pentachloride oxidations (p. 165). 

We will illustrate these rules by naming a few compounds. For example, the compound Nal is called sodium iodide. It contains Na (the sodium cation, named for the parent metal) and 1 (iodide the root of iodine plus -ide). Similarly, the compound CaO is called calcium oxide because it contains Ca (the calcium cation) and 0 (the oxide anion). 

What are the names, formulas, and electronic structures of the stable oxyacids of iodine and their anions ... 

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