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Intramolecular Diels-Alder Reactions toward Dihydroaromatic and Aromatic Products

3 INTRAMOLECULAR DIELS-ALDER REACTIONS TOWARD DIHYDROAROMATIC AND AROMATIC PRODUCTS [Pg.349]

In the two examples selected, it is quite remarkable that in the gold-catalyzed process, fairly complex starting materials can be employed and that the trans product 39 is formed exclusively. On the other hand, in a rhodium-catalyzed reaction, the cis product 40 is formed as a single diastereomer. Also, in both reactions a broad range of substituents and functional groups were tolerated, which allow further modification of these cycloadducts. [Pg.349]




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And Diels-Alder reactions

Aromatic products

Aromatic products production

Aromaticity Diels-Alder reactions

Aromatics production

Diels intramolecular

Diels intramolecular reaction

Diels reaction/-products

Diels-Alder products

Diels-Alder reaction aromatic

Diels-Alder reaction products

Intramolecular Diels-Alder

Intramolecular reaction and

Product aromatization

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