Inter-conversion of clusters and solid-state materials

Inter-conversion of clusters and solid-state materials 

The conceptual connection between cluster and solid-state chemistries is the unifying theme of the first seven chapters. Complementary empirical connections between cluster and solid-state chemistries are emphasized in this final chapter. That is, the synthesis of solid-state materials from molecular precursors including clusters permits the strengths of molecular synthesis to be used in the development of new materials. On the other hand, the utilization of Zintl clusters as novel reagents in solution permits the advantages of thermodynamically driven solid-state synthesis to be transferred to the production of clusters in solution. Most of the examples discussed could have been included in earlier chapters, but are gathered here to serve as a review as well as a stimulus to creative thought for future research in cluster and materials chemistries. 

---