Inoue generalization

In a similar spirit, Inoue et al. [120] and Hashimoto et al. [121] generalized MPC dynamics so that the collision operator reflects the species compositions in the neighborhood of a chosen cell. More specifically, consider a binary mixture of particles with different colors. The color of particle i is denoted by c,-. The color flux of particles with color c in cell E, is defined as... 

Ihmels H, Otto D (2005) Intercalation of Organic Dye Molecules into Double-Stranded DNA - General Principles and Recent Developments. 258 161-204 Iida H, Krische MJ (2007) Catalytic Reductive Coupling of Alkenes and Alkynes to Carbonyl Compounds and Imines Mediated by Hydrogen. 279 77-104 Imai H (2007) Self-Organized Formation of Hierarchical Structures. 270 43-72 Indelli MT, see Chiorboli C (2005) 257 63-102 Inoue Y, see Borovkov VV (2006) 265 89-146 Ishii A, Nakayama J (2005) Carbodithioic Acid Esters. 251 181-225 Ishii A, Nakayama J (2005) Carboselenothioic and Carbodiselenoic Acid Derivatives and Related Compounds. 251 227-246... 

Kimata A, Kondo T, Ueyama J, Yamamoto K, Kamijima M, Inoue T, Ito Y, Hamajima N (2009) Relationship between dietary habits and urinary concentrations of 3-phenoxybenzoic acid in a middle-aged and elderly general population in Japan. Environ Health Prev Med 14 173-179... 

Obviously, in such cases the CD is acting as a true catalyst in esterolysis. The basic cleavage of trifluoroethyl p-nitrobenzoate by a-CD occurs by both pathways approximately 20% by nucleophilic attack and approximately 80% by general base catalysis (GBC) (Komiyama and Inoue, 1980c). The two processes are discernible because only the former leads to the observable p-nitrobenzoyl-CD. For the ester, Ks = 3.4 mM and kjka = 4.4 for the GBC route (1.25 for the nucleophilic route), and so KTS = 0.77 mM. For reaction within the ester CD complex [28], it was estimated that the effective molarity of the CD hydroxyl anion was 21-210 m (for Br0nsted /3 = 0.4 to 0.6 for GBC). Such values are quite reasonable for intramolecular general base catalysis (Kirby, 1980). 

Although anionic polymerization of cyclic ethers is generally limited to oxiranes, there are reports of successful oxetane and tetrahydrofuran polymerizations in the presence of a Lewis acid. Aluminum porphyrin alone does not polymerize oxetane, but polymerization proceeds in the presence of a Lewis acid [Sugimoto and Inoue, 1999]. Similarly, THF is polymerized by sodium triphenylmethyl in the presence of a Lewis acid such as aluminum alkoxide [Kubisa and Penczek, 1999]. The Lewis acid complexes at the ether oxygen, which weakens (polarizes) the carbon-oxygen bond and enhances nucleophilic attack. 

Dendritic derivatives of these macrocycles can be placed in the wider context of studies on metalloporphyrins with sterically hindered faces which have been designed in attempts to mimic the properties of heme proteins and chlorophylls, and there are suggestions that steric isolation of the metalloporphyrin nucleus is important in certain biological functions, The redox properties of metalloporphyrins are well-documented they are dominated by two, reversible one-electron transfers involving both the metal and the ligand. The first dendritic porphyrins of general structure 47 and their Zn complexes were reported by Inoue et al. who... 

Activation of an M-CO bond for nucleophilic substitution in anion radical metallo-complexes appears to be quite a general effect (Kaim 1987 Mao et al. 1989,1992 Shut et al. 1995 Klein et al. 1996). Such activation seems to be the basis of metal-cluster catalytic activity. The iron-sulfur cluster (Bu4N)2Fe4S4(SPh)4 deserves to be mentioned here. The cluster is considered as a ferredoxin model (Inoue Nagata 1986) it catalyzes an electron transfer from //-butyl lithium or phenyl lithium to 5-phenyl thiobenzoate or phenylbenzoate (Inoue Nagata 1986). 

The Inoue-catalyst 1 tolerates exchange of phenylalanine for leucine, affording the catalytically active diketopiperazine cyclo-(S)-His-(S)-Leu (2, Scheme 6.3) [33], As shown in Scheme 6.3, addition of HCN to benzaldehyde and derivatives can be catalyzed by both 1 and 2. It should, however, be noted that the configurations of the cyanohydrins obtained were opposite, depending on whether 1 or 2 was employed as catalyst. With aliphatic aldehydes the diketopiperazine 1 generally affords rather poor enantioselectivity (< 50% ee) [19]. In contrast, catalyst 2 afforded ee as high as 81% for aliphatic aldehydes (Scheme 6.3) [33], The absolute configuration of the product cyanohydrin was determined only for n-butyraldehyde as substrate (not shown in Scheme 6.3) and found to be R [33],... 

As Makino, Inoue and Tsuiuta (5i) have reported, the ratio r of the reactivity of monomer (NCA) antipodes is generally expressed by the following equation ... 

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