Inorganic oxides agent reactions

Strecker degradation. Interaction of an a-amino acid with a carbonyl compound in aqueous solution or suspension to give carbon dioxide and an aldehyde or ketone containing one less carbon atom. Inorganic oxidizing agents can also be used to bring about the reaction. 

Elimination of two H atoms requires inorganic oxidizing agents, such as KoCr Oy in aqueous H2SO4. The reaction oxidizes the HC—OH group to the C=0 group (shown with condensed and carbon-skeleton fonnulas) ... 

The most common way to convert LP polymers to solid elastomers is to couple the terminal -SH groups. This is done either by oxidation to disulfides using organic or inorganic oxidizing agents or by reaction with epoxy resins, aromatic amines, diisocyanates, aldehydes, etc [16,35] ... 

CIO2 is a strong oxidizing agent towards both organic and inorganic materials and it reacts readily with S, P, PX3 and KBH4. Some further reactions are in the scheme overleaf ... 

According to Kirk Othmer (Ref 34), the reactions of nitric acid may be classified conveniently into three groups (l) reactions as an acid (formation of inorganic nitrates) (2) reactions as an oxidizing agent and (3) organic reactions... 

The same situation is found in the oxidation of certain dissolved reducing agents in many cases these reactions occur only by reaction with oxidizing agents, not on anodic polarization of an electrode. Such behavior is observed primarily in systems with organic reactants, more rarely in systems with inorganic reactants. 

With regard to eqn. (2), which represents the metal deposition half reaction in electroless deposition, in a simplistic sense we see that it is analogous to an electrodeposition process. With respect to the reducing agent reaction, organic [20, 21] and relatively complex inorganic oxidation reactions [22] have similarly been widely studied electrochemically. It is therefore reasonable to think that electroless deposition could be described, or modeled, using an electrochemical approach. 

Nitrosyidisulfonic acid, reaction mechanisms, 22 129, 130 Nitrous acid, 33 103 decomposition, rate constants, 22 157 as oxidizing agent, 22 133 reaction mechanisms, 22 143-156 electrophilic nitrosations, 22 144-152 with inorganic species, 22 148, 149 nitrite oxidation by metals, 22 152-154 oxidation by halogens, 22 154, 155 in solution, 22 143, 144 reduction by metals, 22 155, 156 Nitrous oxide reductase, 40 368 Nitroxyl, reaction mechanisms, 22 138 Nitrozation, pentaamminecobalt(III) complexes, 34 181... 

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