Reactions with Inorganic Compounds

Decomposition evolves oxygen. Periodates are noncombustible substances but ignite when mixed with combustible materials. Fire and/or explosion may occur when periodates are mixed with organics or other readily oxidizable compounds. Reactions with finely divided metals, hydrides, mineral acids, charcoal, phosphorus, alkyl phosphites, amines, sulfur, and a number of inorganic and organic compounds can be violently explosive. 

This book provides a detailed, up to date account of the reactions of chlorosulfonic acid with aliphatic, aromatic and heterocyclic compounds reactions with elements and inorganic compounds are also discussed, along with the use of the reagent as a powerful acid catalyst and a halc eiution and dehydrating agent. Finally, the commercial uses and manufacture of chlorosulfonic acid are reviewed. 

Polythiodipropionic acids and their esters are prepared from acryUc acid or an acrylate with sulfur, hydrogen sulfide, and ammonium polysulfide (32). These polythio compounds are converted to the dithio analogs by reaction with an inorganic sulfite or cyanide. 

Reactions With Inorganic Compounds. In an investigation of the reactions of BrF with oxides (71—73), Httle or no reaction was found with the oxides of Be, Mg, Ce, Ca, Fe, Zn, Zr, Cd, Sn, Hg, Th, and the rare earths, whereas the oxides of Mo and Re formed stable oxyfluorides. 

Electrolysis of fluorosulfuric acid produces either S20 E2 [13709-32-5] (24) or SO2E2 [13036-75 ] plus OE2 (25), depending on specific conditions. Various reactions of fluorosulfuric acid with inorganic compounds are shown in Table 2, and with organic compounds in Table 3. 

The term Grignard reaction refers to both the preparation of a class of organomagnesium haUde compounds and their subsequent reaction with a wide variety of organic and inorganic substrates. As such it has had a wide and profound influence on synthetic chemistry since its first elucidation by Victor Grignard at the beginning of the twentieth century. 

Reaction with Other Inorganic Halogen Compounds. Anhydrous HCl forms addition compounds at lower temperatures with halogen acids such as HBr and HI, and also with HCN. These compounds are stable at room temperature. 

Reaction with Inorganic Compounds. Most metals and alloys react with aqueous hydrochloric acid via... 

Reactions with Elements and Inorganic Compounds. Aluminum reacts with oxygen [7782-44-7] having a heat of reaction of... 

A convenient synthesis of organochlorosilanes from organosilanes is achieved by reaction with inorganic chlorides of Hg, Pt, V, Cr, Mo, Pd, Se, Bi, Fe, Sn, Cu, and even C. The last compounds, tin tetrachloride, copper(II) chloride, and, under catalytic conditions, carbon tetrachloride (117,118), are most widely used. 

The physical properties of elemental sulfur can be modified by its reaction with various organic and inorganic compounds. Many of the resulting sulfur products tend to have properties similar to paving asphalt (49,50). 

Table 2. Reactions of CI2O With Inorganic Compounds...

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