Inerts purge

One version of UOP purge IsoSiv for to naphtha employs inert-purge cycle (64). UOP also developed a similar process, OlefinSiv, for the... 

Regenerative adsorption units can be operated by a thermal-swing cycle, pressure-swing cycle, displacement-purge cycle, or inert-purge cycle. Combinations of these are frequently employed. 

Removal of metal chlorides from the bottoms of the Hquid-phase ethylene chlorination process has been studied (43). A detailed summary of production methods, emissions, emission controls, costs, and impacts of the control measures has been made (44). Residues from this process can also be recovered by evaporation, decomposition at high temperatures, and distillation (45). A review of the by-products produced in the different manufacturing processes has also been performed (46). Several processes have been developed to limit ethylene losses in the inerts purge from an oxychlorination reactor (47,48). 

FIG. 16-40 Ideal inert-purge swing cycle. Reprinted with permission of UOP.)... 

Provide continuous inert purge to check for leaks before start-up... 

Maintain good operating and cleaning procedures Provide fixed water spray, if appropriate Use inherently safe material, where possible Provide inert purge... 

Use Figure 1 to determine the quantity of inert purge gas required. 

Inert purging This refers to the displacement of fuel gas or air with inert gas (complete displacement) or the formation of a barrier of inert gas (less than 4 per cent oxygen) between fuel gas and air during purging (slug purging) ... 

Gas to inert, purge complete with combustibles levels less than 7 per cent. 

Process upset or purge failure The unit relies on inert purging to keep it out of the flammable range, so a penalty of 0.30 is applied. 

While inert and displacement purge regeneration is widely used in liquid phase separations, there are few industrially relevant inert purge systems employed in gas phase separations. It is sufficient to note that an inert purge regeneration can be done and it will generally be most effective at relatively high adsorption temperatures. 

Inert-Purge Cycle. In this cycle, the adsorbate, Instead of being removed by temperature Increase, is removed by passing a non-adsorbing gas containing no adsorbate through the bed. 

Displacement-Purge Cycle This cycle, which is somewhat similar to the previous one, differs from it in that a gas or vapor which adsorbs about as strongly as the adsorbate is used to remove the adsorbate (see Figure 1) Removal is thus facilitated both by adsorbate partial-pressure reduction in the fluid around the particles and by competitive adsorption of the displacement medium. As with the inert-purge cycle, the maximum delta loading is the equilibrium loading ... 

Combined Cycles Often a temperature-swing cycle is combined with an inert-purge to further facilitate desorption. Several possibilities are shown in Figure 2. The inert-purge stream can be a fraction of the less-adsorbed product, or a separate purge stream can be used If the feed is at super-atmospheric pressure, many times the desorption step will be carried out at atmospheric pressure. 

Gas bulk-separation processes consist mostly of pressureswing adsorption (PSA) variations and displacement-purge and Inert-purge processes Recently, however, a chromatographic cycle has been commercialized Below, these cycles will be discussed ... 

Displacement-Purge and Inert-Purge Cycles By far the most widespread embodiment of these cycles Is the separation of normal and lso-parafflns In a variety of petroleum fractions. These fractions In general contain several carbon numbers and can Include molecules from about C5 to about C g All of these separations use 5A molecular sieve as the adsorbent Its 0.5 nm pore diameter Is such that normal paraffins can enter but lso-parafflns are excluded this constitutes the basis for separation. 

Compared to adsorption s use in bulk-gas separations, its use in gas purifications is much more frequent (see Table I and references 13, 36 and 37), and the technology is, for the most part, more conventional Temperature-swing adsorption, often combined with inert-purge stripping, is by far the most common process used Two or more fixed beds operated in parallel, typically with one adsorbing and one or more regenerating, constitute the standard flowsheet ... 

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