INDEX Acetylide

CYANO COMPOUNDS, DIENES, HALOACETYLENE DERIVATIVES, HALOGEN OXIDES, METAL ACETYLIDES, METAL FULMINATES, OXIDES OF NITROGEN The individually indexed endothermic compounds, for most of which heats of formation are given in the text f Acetonitrile, 0758... 

Several explosive salts including the acetylide, azide, borate, bromate, chlorate, chromate, iodate (and ammonium iodate double salt), nitrite, perchlorate (and ammonium perchlorate double salt), periodate, permanganate, picrate and trinitrobenzoate were prepared. The 3 latter salts and the acetylide, azide and bromate are impact-sensitive detonators [1], It appears probable that many of the explosively unstable compounds [2], formed in various ways from interaction of mercury or its compounds with ammonia or its salts, may have the common polymeric structure now recognised for Millon s base [3], This is a silica-like network of N+ and Hg in 4- and 2-coordination, respectively, with OH and water in the interstitial spaces. Individually indexed compounds are Poly(dimercuryimmonium acetylide)... 

The remaining individually indexed eompounds are Almninium, 0048 Ammonimn phosphinate, 4554 Barimn phosphinate, 0210 t Benzaldehyde, 2731 1,4-Benzenediol, 2333 =N Bis(hydrazine)tin(ll) ehloride, 4070 Calcium acetylide, 0585 Calcium phosphinate, 3931 Chromium(Il) ehloride, 4052 Chromium(ll) oxide, 4241 Chromium(ll) sulfate, 4244 Copper(I) bromide, 0265 Diacetatotetraaquoeobalt, 1780 Diisobutylalmninimn hydride, 3082 t 1,2-Dimethylhydrazine, 0955... 

Multinuclear acetylide complexes containing two or three Pd-Pt p-ethynediyl units have been prepared and applied as multifunctional initiators for the living polymerisation of aryl isocyanides, giving two- or three-armed poly(isocyanide)s with a narrow polydispersity index. A similar Pd-Pt i-ethynediyl complex has been used an an initiator in the polymersation of aryl isocyanide bearing... 

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