INDEX Acetylenic alcohols

Examples of alkylation, dealkylation, homologation, isomerization, and transposition are found in Sections 1, 17, 33, and so on, lying close to a diagonal of the index. These sections correspond to such topics as the preparation of acetylenes from acetylenes carboxylic acids from carboxylic acids and alcohols, thiols, and phenols from alcohols, thiols, and phenols. Alkylations that involve conjugate additions across a double bond are found in Section 74 (alkyls, methylenes, and aryls from olefins). 

Examples of the protection of acetylenes, carboxylic acids, alcohols, phenols, aldehydes, amides, amines, esters, ketones, and olefins are also indexed... 

Properties Heavy, colorless, corrosive liquid chloroform-like odor. D 1.593 (25/25C), bp 146.5C, fp —43C, bulk d 13.25 lb/gal (25C), refr index 1.4918 (25C), flash p none. Soluble in alcohol and ether slightly soluble in water. Nonflammable. Derivation Reaction of acetylene and chlorine and subsequent distillation. 

How to Use the Book to Locate Examples of the Preparation of Pj-o-tection of Monofunctional Compounds. Examples of the preparation of one functional group from another are found in the monofunctional index on p xiii, which lists the corresponding section and page. Sections that contain examples of the reactions of a functional group are found in the horizontal rows of this index. Section 1 gives examples of the reactions of acetylenes that form new acetylenes Section 16 gives reactions of acetylenes that form carboxylic acids and Section 31 gives reactions of acetylenes that form alcohols. 

Sections giving examples of the reactions of a functional group are found in horizontal rows of the index. Thus Section 1 gives exampies of the reactions of acetylenes forming other acetylenes Section 16, reactions of acetylenes forming carboxylic acids Section 31, reactions of acetylenes forming alcohols etc. 

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