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Impact surfaces correcting

At the time the experiments were perfomied (1984), this discrepancy between theory and experiment was attributed to quantum mechanical resonances drat led to enhanced reaction probability in the FlF(u = 3) chaimel for high impact parameter collisions. Flowever, since 1984, several new potential energy surfaces using a combination of ab initio calculations and empirical corrections were developed in which the bend potential near the barrier was found to be very flat or even non-collinear [49, M], in contrast to the Muckennan V surface. In 1988, Sato [ ] showed that classical trajectory calculations on a surface with a bent transition-state geometry produced angular distributions in which the FIF(u = 3) product was peaked at 0 = 0°, while the FIF(u = 2) product was predominantly scattered into the backward hemisphere (0 > 90°), thereby qualitatively reproducing the most important features in figure A3.7.5. [Pg.878]

The correct selection of the kind of surface treatments renders possible very high HDT values (80°C) with impact of about 50 % of virgin polypropylene or, alternatively, lower HDT values (65°C) with the impact of about 70 % of virgin polypropylene. Even the latter kind of PP/Mg(OH)2 has an HDT value higher than that of virgin polypropylene (55 °C). [Pg.340]

FIGURE 12.18 Corrected water table piezometer surface contour map showing regional hydrogeologic gradient toward the southwest. Note the impact of recovery systems within their area of influence or capture zones. (After Testa et al., 1989.)... [Pg.372]

The exponential dependencies in Eq. (14-195) represent averages of values reported by a number of studies with particular weight given to Lefebvre ([.Atomization and Sprays, Hemisphere, New York (1989)]. Since viscosity can vary over a much broader range than surface tension, it has much more leverage on drop size. For example, it is common to find an oil with 1000 times the viscosity of water, while most liquids fall within a factor of 3 of its surface tension. Liquid density is generally even closer to that of water, and since the data are not clear that a liquid density correction is needed, none is shown in Eq. (14-195). Vapor density also has an impact on dropsize but the impact is complex, involving conflicts of a number of effects, and vapor density is commonly omitted in atomizer dropsize correlations. [Pg.93]

It is important to realize that corrosion rates may be controlled by any of several thermodynamic or kinetic properties of the alloy-scale-environment system and not just by surface or interface reactions. The three stages of high temperature oxidation of a metal, shown schematically in Fig. 1, serve as an example (7). The first or transient stage includes initial gas adsorption, two-dimensional oxide nucleation, initial three-dimensional oxide formation and finally, formation of the dominant oxide that will control the oxidation rate in Stage II. Various portions of Stage I have been widely studied using surface analytical techniques, but its duration can be very short and it is usually assumed (not always correctly) that Stage I has little impact on ultimate corrosion properties of the material. [Pg.253]

These needs led in turn to investigation of ways of preparing synthetic surfaces so that in behaviour they would be very similar to natural lawn or turf. The factors examined in this connection included the heights to which sports balls would rebound, the resistance to balls rolled over the surface ( ball drag ), and the absorption of impact. All were found to depend largely on the method of construction of the synthetic surface, including its underlayers—the correct... [Pg.109]


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