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Hydrogen bonds/bonding anionic linkers

Beer and coworkers have modified their approach by derivatizing the upper rim of calix[4]arene with two (48, Tos = tosylate) and four (49) Ru(II) tris-bipyridyl reporter sites. The amide linkers of 48 and 49 form a hydrogen-bonding cleft for anion occupation. A preliminary report [385] indicates that MLCT luminescence from the Ru(II) centers is sensitive to anion association. [Pg.55]

FIGURE 23. The extensive supramolecular network involving intrachain and interchain O-H- -O hydrogen bonding in the compound [Cu (2,2 -bipy)(H20)2Cl] [Cu°(2,2 -bipy)(H20)2Al(OH)6Mo60i8] -41120. The Anderson anions are shown in polyhedral representation. Color code Al, cyan Mo, yellow O, red Cu, purple H, white circle. The bip5Tidine ligands, coordinated to Cu(Il) linkers, are not shown here for clarity (Reprinted with permission from ref. 45.)... [Pg.84]


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See also in sourсe #XX -- [ Pg.480 ]




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Anions hydrogenation

Hydrogen anions

Hydrogen bonding anions

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