Hydrocarbons mechanisms

Cavalieri, E. Rogan, E. Warner, C. Bobst, A. In "Polynuclear Aromatic Hydrocarbons Mechanisms, Methods and Metabolism" Cooke, M. Dennis, A.J., Eds. Battelle Press, Columbus, Ohio, in press. 

Eadie, B.J., W.R. Faust, P.F. Landrum, and N.R. Morehead. 1984. Factors affecting bioconcentration of PAH by the dominant benthic organisms of the Great Lakes. Pages 363-377 in M. Cooke and A.J. Dennis (eds.). Polynuclear Aromatic Hydrocarbons Mechanisms, Methods and Metabolism. Battelle Press, Columbus, OH. 

At high pressures or in the initial stages of hydrocarbon oxidation, high concentrations of H02 can make reaction (3.45) competitive to reaction (3.44), so reaction (3.45) is rarely as important as reaction (3.44) in most combustion situations [4], Nevertheless, any complete mechanism for wet CO oxidation must contain all the H2—02 reaction steps. Again, a complete mechanism means both the forward and backward reactions of the appropriate reactions in Appendix C. In developing an understanding of hydrocarbon oxidation, it is important to realize that any high-temperature hydrocarbon mechanism involves H2 and CO oxidation kinetics, and that most, if not all, of the C02 that is formed results from reaction (3.44). 

The essential point is that the initiation steps provide H atoms that react with the oxygen in the system to begin the chain branching propagating sequence that nourishes the radical reservoir of OH, O, and H that is, the reaction sequences for the complete H2—02 system must be included in any high-temperature hydrocarbon mechanism. Similarly, when CO forms, its reaction mechanism must be included as well. 

Dreibelbis WG, Ealy JA, Porter WE. 1985. Industrial hygiene monitoring forevaluation of employee exposure and control measures in coal conversionprogram at Oak Ridge National Laboratory. In Cooke M, Dennis AJ, ed.Polynuclear aromatic hydrocarbons Mechanisms, methods and metabolism.Columbus, OH Battell Press, 351-363. 

Sangaiah, R., and A. Gold, A Short and Convenient Synthesis of Cyclopenta[cd]pyrene and Its Oxygenated Derivatives, in Polynuclear Aromatic Hydrocarbons Mechanisms, Methods and Metabolism (M. Cooke and A. J. Dennis, Eds.), Eighth International Symposium on Polynuclear Aromatic Hydrocarbons, Bat-telle Press, Columbus, OH, 1985. 

Russell GA (1957) Deuterium-isotope effects in the autoxidation of aralkyl hydrocarbons. Mechanism of the interaction of peroxy radicals. J Am Chem Soc 79 3871-3877... 

Oxidation of hydrocarbons - mechanism and steady state analysis, 229-232 A stylised branched chain mechanism - a steady state analysis, and kinetic criteria for the explosive region, 246-249... 

Biosynthesis ofcuticular hydrocarbons Mechanism of hydrocarbon formation... 

Most of the generated reactions were eliminated during the construction of the mechanism. The primary tool was the comparison of reaction rates for parallel reaction channels. This approach required careful planning of the order of generation of the reaction types. The program was used for the pyrolysis of C1-C4 hydrocarbons. Mechanisms for ethane, propane and butane contained 15, 49 and 76 species and 18, 115 and 179 reactions, respectively. These mechanisms were compared with schemes which had been proposed by human experts. Most of the reactions were identical, and, in general, the program proposed a superset of those presented in the literature. 

Russell, G. A. Deuterium-isotope Effects in the Autoxidation of Aralkyl Hydrocarbons. Mechanisms of the Interaction of Peroxy Radicals. /. Am. Chem. Soc. 79 3871, 1957. 

Eisenberg WC, Cunningham DLB. 1985. Analysis of polycyclic aromatic hydrocarbons in diesel emissions using high performance liquid chromatography A methods development study. In Cook M, Dennis AJ, eds. Polynuclear aromatic hydrocarbons Mechanisms, methods and metabolism. Columbus, OH Battelle Press, 379-393. 

Gorman R, Liss GM (1984) Occupational exposure to pitch in a non-heated process, phototoxicity, and pre-malignant warts. In Cooke M, Dennis AJ (eds) Polynuclear aromatic hydrocarbons mechanism, methods and metabolism. Battelle Press, Columbus, pp 497-508... 

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