Hydrides of Silicon, Germanium, Tin, and Lead

454 Feher, P. Hadicke, and H. Frings, Inorg. Nuclear Chem, Letters, 1973, 9, 931. 

MeaSiSiHs + Me,SiSiHa(Me) + MegSiSiH(OMe)a + McaSiSifOMela Reagents i, HI ii, LiAlH iii, MeOH 

7) are effectively catalysed by chlorotris(triphenylphosphine)rhodium(i) and dichloro(triphenylphosphine)ruthenium(n), providing a selective route to diarylalkoxysilanes. A variety of dihalogenodiphosphinenickel(u) com- 

Kumada, K. Tamao, and M. Umeno,/. Organometallic Chem., 1973,50, 

Kumada, K. Maeda, K. Sumitani, and K. Tamao, /. Organometallic 

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Lukevics, E. and Voronkov, M. G., Addition Products from Organic and Inorganic Hydrides of Silicon, Germanium, Tin and Lead, Izd. Akad. Nauk Latv. SSSR, Riga, 1904.. 

Of all the reactions studied, only the synthesis of nitrogen oxides and acetylene in arcs or plasma torches and that of ozone in glow and corona discharges are of major importance. In addition, a few small-scale preparations of inorganic compounds have been developed, e.g. synthesis of hydrazine and of hydrides and halides of silicon, germanium, tin, lead, phosphorus or arsenic 3> ... 

This Table names a large number of homoatomic and binary compounds and species, and some heteropolynuclear entities, and thus may be used as a reference for names of simple compounds and a source of examples to guide in the naming of further compounds. It may be necessary to browse the Table to find (families of) compounds that match those of interest. For example, all the oxides of potassium are named corresponding compounds of the other alkali metals, not included here, are named analogously. Several silicon and germanium hydride species are named names for corresponding tin and lead species are not necessarily included. 

Similarly, the reactions of olefins with metal hydrides, such as silicon hydrides, germanium hydrides, tin hydrides and lead hydrides, were also found. These reactions are called hydrosilylation, hydrogeimanation, hydrostannation and hydroplumbylation, respectively. These reactions easily proceed even if the R in eq. (2.28) are functional groups. Then these reactions are conveniently used for syntheses of organometallic compounds having a functional group by a one-stage reaction. 

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