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Hydrazines 6-hydroxy

Hydrazin (6-Hydroxy-2,3,5-trichlor-phenyl)- E16a, 668 (aus dem Hydrochlorid)... [Pg.258]

N-Hienyl-N-beiizyl-hydrazin-hydroxy allylat 16II245. [Pg.1095]

Preliminary indication of the presence of a phenol ester may be obtained by heating the compound with soda-lime esters of phenols and also aromatic hydroxy-acids usually give the phenol. (Likewise amides, Imides, nitriles, substituted hydrazines, uretheines, etc. eifiord ammonia.)... [Pg.1064]

Supplement 1942 195-449 Hydroxy-amines Aminoethyl alcohol, 274. Carbonyl-amines Aminoacetaldehyde, 307. Aminoacetone, 314. Hydroxy-carbonyl amines Glucosamine, 328. Aminocarboxylic acids Glycine, 333. Hydroxylamines, 534. Hydrazines, 546. Azo Compounds. 562. Oryano-metallic Compounds, 580. [Pg.1119]

Supplement 1953 3242-3457 Hydroxy-carboxylic acids, 190 In i doxylic acid, 226. Carbonyl-carboxylic acids, 284. i Sulphonic acids, 386 Quinoline sul-phonic acid, 390. Amines, 419 2-Aminopyridine, 428. Amino-carboxylic acids, 541 Tryp- tophane, 545. Hydrazines, 563. Azo. compounds, 572. Diazo compounds, 590. ... [Pg.1124]

Benzeneamine, N-hydroxy-N-nitroso,ammonium salt Nitrilotrlacetic acid 4,4 -Thiodianiline Ethyl acrylate Butyl acrylate Ethyleneimine (Aziridine) p-Nrtrosodiphenylamine Calcium cyanamide Hydrazine Aldrin... [Pg.65]

A solution of bismuth trioxide in hot glacial acetic acid provides a specific method for the oxidation of acyloins. " The reaction rate is dependent on the steric accessibility of the ketol system. A 2,3-ketol requires less than one hour for completion but an 11,12-ketol is not yet fully oxidized in thirty hours." The reaction is highly selective as a-keto acids, hydrazines and phenols are not oxidized. In a direct comparison with cupric acetate, this procedure is somewhat superior for the preparation of a 2,3-diketone from a 2-keto-3-hydroxy steroid. ... [Pg.250]

The azidohydrins obtained by azide ion opening of epoxides, except for those possessing a tertiary hydroxy group, can be readily converted to azido mesylates on treatment with pyridine/methanesulfonyl chloride. Reduction and subsequent aziridine formation results upon reaction with hydrazine/ Raney nickel, lithium aluminum hydride, or sodium borohydride/cobalt(II)... [Pg.27]

Both 1- and 2-naphthylhydrazine have been shown to react in good yield with 2-hydroxy-3-naphthoic acid in the presence of sodium bisulfite to give, after acidic workup, dibenzocarbazole 30 and 31, respectively7 When either 1- or 2-naphthylhydrazine is heated with sodium bisulfite, dibenzocarbazoles 32 and 31, respectively, are isolated after acidic work-up7 It is suggested that loss of the hydrazine residue to form a bisulfite addition compound of the parent naphthol occurs initially further reaction of this adduct with naphthylhydrazine then affords, after work-up, the products. [Pg.113]

Reaction of 2,4-dichloro-l,5-naphthyridine with ammonia (170°, 20 hr), hydrazine (100°, 16 hr), or aqueous hydrochloric acid (100°, 3 hr) was shown to yield the 2-amino- (47% yield) and 2-hydroxy-4-chloro derivatives (66% yield), but 2-hydrazino substitution (68% yield) was assumed. Disubstitution with ammonia (190°, 4 hr), hydrazine (100°, 48 hr), and ammonia-phenol (180°, 6 hr) occurred in high yield. Displacement of the 4-oxo group in 2,4-dioxo-l,5-naphthyridine occurs with aniline plus its hydrochloride (180°, 12 hr, 88% yield) to yield 429. Oxo groups in the 2- or 4-positions were... [Pg.378]

The 1,2,4-triazine 4-oxides 55 were synthesized by the reaction of nitrones 158 (generated from a-hydroxylamino ketones and aldehydes) with an excess of hydrazine, followed by the oxidation of the intermediate 4-hydroxy-2,3,4,5-tetrahydro-l,2,4-triazines 159 with lead(TV) oxide (73KGS134). [Pg.297]

Hydrazone of 1 -hydrazino-1 -hydroxy-4-phenyl-1,2-dihydro-3//-pyrido [l,2-c]pyrimidin-3-one was patented as cross-linkers for making physiologically compatible and H2O insoluble hydrazine or hydrazono compounds (97JAP(K)97/59303). [Pg.263]

In a scheme intended to produce a more highly substituted oxazolidone, epichlorohydrin is condensed with morpholine in the presence of strong base to give the aminoepoxide, 27. Ring opening of the oxirane by means of hydrazine gives the hydroxy-hydrazine (28). Ring closure with diethyl carbonate leads to the substituted oxazolidone (29). Condensation with 18 affords furaltadone (30). ... [Pg.229]

Cyclohexanone gives c-caprolactone, bp 102-10477 mm, which may polymerize on standing. The lactone may be converted easily to the corresponding e-hydroxy-hydrazide by heating on a steam bath with a slight excess of 100% hydrazine hydrate. The crude hydrazide may be recrystallized from ethyl acetate, mp 114-115°. [Pg.10]

The 17tt,20,20,21-bis(methylenedioxy )-11 (3-hydroxy-2-hydroxy methylene-6,16a-dimethyl-4,6-pregnadiene-3-one (1.19 g) is dissolved In 25 cc of ethanol. 300 mg of phenyl hydrazine is added and the mixture is refluxed under nitrogen for one hour. About 25 cc of water is added. The product is then extracted into 150 cc of ether. The extracts are washed with 2N HCI, with saturated sodium bicarbonate, water and saturated sodium chloride solution, and then dried over sodium sulfate and evaporated to dryness to give about 1.2 g... [Pg.391]

In recent years, possible alternatives to hydrazine have been suggested, and some have been used on plant. These include carbohydrazide (NH2NHCONHNH2), derivatives of hydroxylamine, e.g. diethyl hydroxy-lamine (HONfCiHjIi), ketoximes, and erythrobic acid (iso corbic acid). These are usually faster scavengers than hydrazine or activated hydrazine . [Pg.840]

However, in some cases azines can be converted to hydrazones by treatment with excess hydrazine and NaOH. Arylhydrazines, especially phenyl, p-nitrophenyl, and 2,4-dinitrophenyl, are used much more often and give the corresponding hydrazones with most aldehydes and ketones.Since these are usually solids, they make excellent derivatives and are commonly employed for this purpose. Cyclic hydrazones are also known, ° as are conjugated hydrazones. a-Hydroxy aldehydes and ketones and ot-dicarbonyl compounds give osazones, in which two adjacent carbons have carbon-nitrogen double bonds ... [Pg.1193]


See other pages where Hydrazines 6-hydroxy is mentioned: [Pg.251]    [Pg.995]    [Pg.1933]    [Pg.54]    [Pg.222]    [Pg.58]    [Pg.160]    [Pg.589]    [Pg.766]    [Pg.267]    [Pg.62]    [Pg.26]    [Pg.202]    [Pg.228]    [Pg.205]    [Pg.380]    [Pg.384]    [Pg.92]    [Pg.105]    [Pg.118]    [Pg.136]    [Pg.144]    [Pg.170]    [Pg.822]    [Pg.63]    [Pg.709]    [Pg.103]    [Pg.104]    [Pg.136]    [Pg.159]    [Pg.215]    [Pg.223]    [Pg.252]    [Pg.1411]   
See also in sourсe #XX -- [ Pg.19 , Pg.465 ]




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