High-temperature, oxidative stability

Such hybrid molecules and supramolecular solids offer the promise of systems with the flexibility, strength, toughness, and ease of fabrication of polymers, with the high temperature oxidative stability of ceramics, and the electrical or catalytic properties of metals. Polyphosphazene chemistry provides an illustration of what is possible in one representative hybrid system. 

At present, high-temperature stabilization of polyolefins is still misunderstood besides, this problem presents serious difficulties. Stabilization of thermal oxidation and photoinduced destruction with the use of stabilizers in this case is inefficient, since at high temperatures these stabilizers are easily evaporated out of the polyolefin melt and decomposed with the formation of radicals capable of initiating additional kinetic chains of destruction. 

In the broadest sense, coordination chemistry is involved in the majority of steps prior to the isolation of a pure metal because the physical properties and relative stabilities of metal compounds relate to the nature and disposition of ligands in the metal coordination spheres. This applies both to pyrometallurgy, which produces metals or intermediate products directly from the ore by use of high-temperature oxidative or reductive processes and to hydrometallurgy, which involves the processing of an ore by the dissolution, separation, purification, and precipitation of the dissolved metal by the use of aqueous solutions. 4... 

His research interests are generally in high-temperature and solid-state chemistry of materials, including electrochemical devices (e.g., chemical sensors and fuel cells) and the chemical stability of materials (e.g., high-temperature oxidation). Dr. Fergus is an active member of the Electrochemical Society, the Metals, Minerals and Materials Society, the American Ceramics Society, the Materials Research Society, and the American Society for Engineering Education. 

Varghese OK, Gong DW, Paulose M, Grimes CA, Dickey EG (2003) Giystallization and high-temperature structural stability of titanium oxide nanotube arrays. J Mater Res 18 156-165... 

Today, silicones have become virtually irreplaceable materials worldwide and have an extremely wide range of applications. The use of silicone room-temperature vulcanising (RTV) elastomers in the construction industry originated in the early 1960s. The value of silicone RTV elastomers is based on important properties such as their thermal stability, unusual surface properties, water repellency, high permeability, oxidative stability and ultraviolet (UV) resistance (Cash, 1970). 

Esters of trimellitic (1,2,4-benzenetricarboxylic acid) anhydride provide excellent resistance to volatile loss and oxidation under heat ageing conditions making them the material of choice in applications for which high-temperature thermal stability is required. Insulation for automotive and aircraft cables are typical areas of application. The low volatility of trimellitates is also exploited in car interior components. 

High Temperature (Thermal) Stability. The high temperature stability of the Shale-I jet fuels was measured using the JFTOT technique (8 ). The thermal oxidative stability of the received fuel (976 ppm N) was measured. The fuel was then acid extracted, the isolated basic nitrogen compounds added back into the extracted shale fuel in varying quantity, and the thermal oxidative stability redetermined. A petroleum derived JP-5 was also subjected to JFTOT... 

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