HEXAHYDRO-2- -AZOCINONE

Azocin-2( 1H )-one, hexahydro- 1-phenyl-photochemical rearrangement, 7, 656 Azodn-2( 1H )-one, 1,2,7,8-tetrahydro-synthesis, 7, 662 Azocin-5-one IR spectra, 7, 16 transannular interactions, 7, 14 Azocin-5-one, l-(2,4-dimethylphenyl)-IR spectrum, 7, 657 Azocin-5-one, methoxycarbonyl-synthesis, 7, 657 Azocin-5-one, 1-methyl-IR spectrum, 7, 657 synthesis, 7, 657 Azodn-5-one, 1-p-tolyl-IR spectrum, 7, 657 Azocinones... 

Further investigation of the Okinawan sponge Haliclona sp. resulted in the isolation of manzamines B-F (182-186), which show cytotoxic activity (152-154). The structures of manzamines B (182) and C (183) were based on X-ray analysis. Manzamine F (186) was found to be identical with keramamine B, the structure of which with a 1,2,3-triazacyclohexane moiety (181) was revised to structure 186 containing a hexahydro-5(2//)-azocinone ring. Total synthesis of manzamine C (183) was achieved by the... 

The procedure described is a one-step conversion of cycloheptanone into hexahydro-2(lH)-azocinone. The method is general and is characterized by good yields, mild conditions, and easy preparation of the product in pure form from readily available starting materials. Several methods are described in the patent literature for simultaneous oximation of ketones and rearrangement to the corresponding oxime, Including the use of hydroxylamine and sulfuric... 

Hexahydro-2(lH)-azocinone 2(lH)-Azocinone, hexahydro- (9) (673-66-5) Hydroxylamine-O-sulfonic acid (8,9) (2950-43-8)... 

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