Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Cleavage, heterolytic

In contrast m a heterolytic cleavage one fragment retains both electrons... [Pg.169]

Step (1) Alkyl halide dissociates by heterolytic cleavage of carbon-halogen bond (Ionization step)... [Pg.218]

The alkyl halide m this case 2 bromo 2 methylbutane ionizes to a carbocation and a halide anion by a heterolytic cleavage of the carbon-halogen bond Like the dissoci ation of an aUcyloxonmm ion to a carbocation this step is rate determining Because the rate determining step is ummolecular—it involves only the alkyl halide and not the base—It is a type of El mechanism... [Pg.218]

Section 5 15 Dehydrohalogenation of alkyl halides by alkoxide bases is not compli cated by rearrangements because carbocations are not intermediates The mechanism is E2 It is a concerted process m which the base abstracts a proton from the p carbon while the bond between the halogen and the a carbon undergoes heterolytic cleavage... [Pg.223]

Heterogeneous reaction (Section 6 1) A reaction involving two or more substances present in different phases Hydro genation of alkenes is a heterogeneous reaction that takes place on the surface of an insoluble metal catalyst Heterolytic cleavage (Section 4 16) Dissociation of a two electron covalent bond in such a way that both electrons are retained by one of the initially bonded atoms Hexose (Section 25 4) A carbohydrate with six carbon atoms High density lipoprotein (HDL) (Section 26 11) A protein that carries cholesterol from the tissues to the liver where it is metabolized HDL is often called good cholesterol Histones (Section 28 9) Proteins that are associated with DNA in nucleosomes... [Pg.1285]

It has recently been suggested that a free radical mechanism i.e., homo-lytic cleavage of the oxygen-oxygen bond rather than the heterolytic cleavage pictured) may be involved in the reaction of some substituted benzophenones and peroxyacetic acid. [Pg.152]

Heterolytic cleavage (Section 4.16) Dissociation of a two-electron covalent bond in such a way that both electrons are retained by one of the initially bonded atoms. [Pg.1285]

First, let us consider the formation of ions from covalently bound species, i.e., the heterolytic cleavage of the covalent (or partially covalent) bond. Charge separation under the influence of the solvent generates an ion pair in a process called ionization this ion pair may then separate into free ions in a dissociation step (Eq. 8-18). [Pg.401]

Compound 104 could not be obtained from 103, and a hypothesis about its formation considered the (homolytic or heterolytic) cleavage of the O—N bond (Scheme 43) (68TL2417). The sensitized reaction didnotgive adifferentresult the author supposed that the reaction involved the excited triplet state of the molecule. When the reaction was carried out in methanol, 104 was obtained in 8% yield... [Pg.78]

In certain cases, e.g. with Z = tert-butyl, the experimental findings may better be rationalized by an ion-pair mechanism rather than a radical-pair mechanism. A heterolytic cleavage of the N-R bond will lead to the ion-pair 4b, held together in a solvent cage ... [Pg.263]

The retrosynthetic operations that we have addressed thus far have not resulted in significant structural simplification. After all, intermediate 6 still possesses a linear fusion of four rings and six contiguous asymmetric carbon atoms. But, nevertheless, intermediate 6 could potentially be derived in one step from intermediate 8, a polyunsaturated monocyclic compound containing only one stereogenic center. Under conditions that would be conducive to a heterolytic cleavage of the C-OH bond in 8, it is conceivable that the resultant tertiary allylic carbonium ion 7 would participate in a... [Pg.86]

Potassium peroxodisulphate (K2S2Og) also oxidizes sulphoxides to sulphones in high yield, either by catalysis with silver(I) or copper(II) salts at room temperature85 or in pH 8 buffer at 60-80 °c86-88. The latter conditions have been the subject of a kinetic study, and of the five mechanisms suggested, one has been shown to fit the experimental data best. Thus, the reaction involves the heterolytic cleavage of the peroxodisulphate to sulphur... [Pg.978]

Dihydroxyacetone phosphate, 210 Dimethyl ether, heterolytic cleavage, 47,48, 53... [Pg.230]

Heterolytic cleavage of the tin-carbon bond is reviewed in references (94-96). Cleavage by electrophiles (e.g, HgXj or halogen) is dominated by electrophilic attack at carbon, and cleavage by nucleophiles principally involves nucleophilic attack at tin. Much of the interest in these processes centers on the intermediate mechanisms that may exist between these extremes, in which electrophilic attack is accompanied by some nucleophilic assistance, and vice versa. Allylic, al-lenic, and propargylic compoimds show a special reactivity by a special (Se2 or SE2y) mechanism. [Pg.10]

In contrast to the abundant examples of radical cleavage, only a few proposals of ionic cleavage of carbon-carbon a bonds have been put forward in the long saga of mechanistic studies on heterolytic cleavage reactions. [Pg.186]

The facile thermal isomerization (17) of norbornadiene derivatives [71]-[77] to cycloheptatrienes in polar solvents has been explained in terms of the initial heterolytic cleavage of the strained C(l)-C(7) bond (Hoffmann and Hauser, 1965 Lemal et al., 1966 Hoffmann, 1971, 1985 Lustgarten and Richey, 1974 Hoffmann et al., 1986 Bleasdale and Jones, 1993). The resulting zwitterion intermediates are stabilized by the cation-stabilizing groups attached to C(7) and the cyclohexadienyl-type delocalization of the negative charge. [Pg.188]

In addition to the cyclic substrates described above, several open-chain compounds are known to undergo heterolytic cleavage of a carbon-carbon tr bond. [Pg.189]

The Ir complexes 83 or [lr(lMes)Cl2Cp ], in the presence of NaOAc and excess of (Bcat), catalyse the diboration of styrene, at high conversions and selectivities for the diborated species, under mild conditions. Other terminal alkenes react similarly. The base is believed to assist the heterolytic cleavage of the (cat)B-B(cat) bond and the formation of Ir-B(cat) species, without the need of B-B oxidative addition [66]. [Pg.40]

The enantioselective P-borylation of a,P-unsaturated esters with (Bpin) was studied in the presence of various [CuCl(NHC)] or [Cu(MeCN)(NHC)] (NHC = chiral imidazol-2-ylidene or imidazolidin-2-ylidene) complexes. The reaction proceeds by heterolytic cleavage of the B-B bond of the (Bpin), followed by formation of Cu-boryl complexes which insert across the C=C bond of the unsaturated ester. Best yields and ee were observed with complex 144, featuring a non-C2 symmetric NHC ligand (Scheme 2.31) [114]. [Pg.56]

Gas-phase Acidity The enthalpy for heterolytic cleavage to form an... [Pg.211]


See other pages where Cleavage, heterolytic is mentioned: [Pg.14]    [Pg.152]    [Pg.157]    [Pg.580]    [Pg.627]    [Pg.78]    [Pg.92]    [Pg.63]    [Pg.63]    [Pg.224]    [Pg.132]    [Pg.138]    [Pg.124]    [Pg.175]    [Pg.205]    [Pg.242]    [Pg.302]    [Pg.381]    [Pg.186]    [Pg.187]    [Pg.143]    [Pg.115]    [Pg.615]    [Pg.285]    [Pg.176]   
See also in sourсe #XX -- [ Pg.274 ]

See also in sourсe #XX -- [ Pg.156 ]

See also in sourсe #XX -- [ Pg.319 ]

See also in sourсe #XX -- [ Pg.33 ]

See also in sourсe #XX -- [ Pg.369 , Pg.371 ]

See also in sourсe #XX -- [ Pg.131 ]

See also in sourсe #XX -- [ Pg.918 ]

See also in sourсe #XX -- [ Pg.4 , Pg.5 , Pg.8 , Pg.9 ]

See also in sourсe #XX -- [ Pg.142 ]

See also in sourсe #XX -- [ Pg.123 ]

See also in sourсe #XX -- [ Pg.156 ]

See also in sourсe #XX -- [ Pg.246 ]

See also in sourсe #XX -- [ Pg.99 , Pg.104 ]

See also in sourсe #XX -- [ Pg.122 ]

See also in sourсe #XX -- [ Pg.12 ]

See also in sourсe #XX -- [ Pg.952 ]

See also in sourсe #XX -- [ Pg.190 ]

See also in sourсe #XX -- [ Pg.147 ]

See also in sourсe #XX -- [ Pg.11 ]

See also in sourсe #XX -- [ Pg.629 ]

See also in sourсe #XX -- [ Pg.212 ]

See also in sourсe #XX -- [ Pg.451 ]

See also in sourсe #XX -- [ Pg.19 , Pg.35 , Pg.36 , Pg.69 , Pg.108 , Pg.109 , Pg.117 , Pg.118 , Pg.120 , Pg.122 , Pg.125 , Pg.126 , Pg.130 , Pg.133 , Pg.135 , Pg.308 , Pg.469 , Pg.475 ]

See also in sourсe #XX -- [ Pg.3 , Pg.4 , Pg.5 , Pg.6 , Pg.7 , Pg.8 , Pg.9 , Pg.10 , Pg.11 , Pg.12 , Pg.13 , Pg.14 , Pg.15 , Pg.16 , Pg.17 , Pg.18 , Pg.19 , Pg.20 ]

See also in sourсe #XX -- [ Pg.29 ]

See also in sourсe #XX -- [ Pg.122 , Pg.176 ]

See also in sourсe #XX -- [ Pg.153 ]

See also in sourсe #XX -- [ Pg.134 ]

See also in sourсe #XX -- [ Pg.49 , Pg.59 ]

See also in sourсe #XX -- [ Pg.493 ]

See also in sourсe #XX -- [ Pg.9 ]

See also in sourсe #XX -- [ Pg.279 ]

See also in sourсe #XX -- [ Pg.250 ]

See also in sourсe #XX -- [ Pg.98 ]

See also in sourсe #XX -- [ Pg.91 ]




SEARCH



And heterolytic bond cleavage

Bond cleavage reactions heterolytic

Bonding heterolytic cleavage

Bonds Homolytic versus Heterolytic Cleavage

Catalytic hydrogenation involving heterolytic cleavage

Cleavage, heterolytic calculations

Collision-induced heterolytic cleavage chromatography

Dihydrogen complexes heterolytic cleavage

Dihydrogen heterolytic cleavage

Dioxygen heterolytic bond cleavage

Heterolytic

Heterolytic Cleavage and Acidity of Coordinated

Heterolytic Cleavage and Acidity of Coordinated Dihydrogen

Heterolytic Cleavage of Coordinated

Heterolytic Cleavage of a Bonds Involving C or

Heterolytic Cleavage to Give Metal-Hydrides

Heterolytic Cleavages. Coupling of Radicals with Nucleophiles

Heterolytic H2 cleavage

Heterolytic bond cleavage

Heterolytic cleavage catalysis

Heterolytic cleavage heterolysis)

Heterolytic cleavage of dihydrogen

Heterolytic cleavage of peroxides

Heterolytic cleavage of the

Heterolytic cleavage silanes

Heterolytic cleavage transition metal complexes

Intermolecular heterolytic cleavage

Intramolecular heterolytic cleavage

Iron compounds heterolytic cleavage

Metal-ligand cleavage, homolytic heterolytic

Peroxide bonds heterolytic cleavage

Proton Cleavage, heterolytic Exchange processes

Radical ions heterolytic cleavage

Reactions heterolytic cleavage

© 2024 chempedia.info