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Hemilabile chelating carbene ligand

Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilabil-ity, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and camphor, derived from amino acids and purines, and they can be used as organocata-lysts mimicking vitamin B1 or as weak solvent donors in lanthanide chemistry. There are many possibilities which are still only scarcely explored. [Pg.5]

Note Isomerism in the ligand sphere ofpalladium(II) carbene complexes with imino functionalised carbene chelate ligands is observed with moderately donating solvents like THF and acetonitrile as the solvent has to be hemilabile itself... [Pg.84]

See other pages where Hemilabile chelating carbene ligand is mentioned: [Pg.474]    [Pg.474]    [Pg.198]    [Pg.75]    [Pg.223]    [Pg.831]    [Pg.246]    [Pg.226]    [Pg.172]    [Pg.176]    [Pg.101]    [Pg.42]    [Pg.86]    [Pg.42]    [Pg.101]    [Pg.3]    [Pg.202]    [Pg.176]   
See also in sourсe #XX -- [ Pg.474 ]



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Carbenes ligands

Chelate ligands

Chelated ligand

Hemilabile

Ligands chelation

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