Grignard organic compounds

Victor Grignard and Paul Sabatier (V. G.) discovery of the Grignard reagent, (P. S.) hydrogenating organic compounds in the presence of finely disintegrated metals... 

Catenated Organic Compounds of the Group IV Elements, 4,1 Conjugate Addition of Grignard Reagents to Aromatic Systems, 1, 221 Cyclobutadiene Metal Complexes, 4, 95 Cyclopentadienyl Metal Compounds, 2, 365 Diene-Iron Carbonyl Complexes, 1, 1... 

Because Me3SiCl 14 is almost inert to lithium organic compounds or Grignard reagents in non-polar solvents, formation of tertiary alcohols on addition of MeLi or n-BuLi to free carboxylic acids [127] or their methyl or ethyl esters [128] in THF... 

Unlike selenobenzophenone, 4 reacts with alkyllithium to afford mainly the corresponding carbophilic adducts, and with Grignard reagents, compounds resulting from addition of the organic radical to sulfur. 

Uses Solvent for oils, waxes, perfumes, alkaloids, fats, and gums organic synthesis (Grignard and Wurtz reactions) extractant manufacture of gun powder, ethylene, and other organic compounds analytical chemistry perfumery alcohol denaturant primer for gasoline engines anesthetic. 

Next you shift your focus to organometallics, those organic compounds that incorporate metals into their structure. Here you study one of the most useful organic reactions, the Grignard reaction. 

Arylation, olefins, 187, 190 Arylketimines, iridium hydrogenation, 83 Arylpropanoic acid, Grignard coupling, 190 Aspartame, 8, 27 Asymmetric catalysis characteristics, 11 chiral metal complexes, 122 covalently bound intermediates, 323 electrochemistry, 342 hydrogen-bonded associates, 328 industrial applications, 8, 357 optically active compounds, 2 phase-transfer reactions, 333 photochemistry, 341 polymerization, 174, 332 purely organic compounds, 323 see also specific complexes Asymmetric induction, 71, 155 Attractive interaction, 196, 216 Autoinduction, 330 Axial chirality, 18 Aza-Diels-Alder reaction, 220 Azetidinone, 44, 80 Aziridination, olefins, 207... 

An important focus of organometallic research has been the development and study of transition metal complexes as catalysts for transformations of organic compounds. These systems enable chemical reactions to occur under conditions that are often milder and more environmentally benign than more traditional routes, such as Lewis acid-catalyzed reactions, Grignard... 

Phosphorus trichloride reacts with organic compounds including Grignard reagents and metal alkyls to give numerous alkyl derivatives. Typical reactions can be illustrated by the following equations ... 

Reactions of metal organic compounds with alkyl halides, such as alkyl-lithium-alkylhalide reactions 2 .c,d,f,h,ii8 -d io) and reactions of Grignard compounds and sodium-naphthalenide D with alkylhalides,... 

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