Graphite phase diagram

III. N2 on Graphite Phase Diagram Submonolayers and Melting Tricritical Point... 

Fig. 4. Reentrant fluid of Kr/graphite. High T region of the Kr/graphite phase diagram (from Ref. 30). The reentrant fluid (RF) phase is a domain wall fluid bounded by commensurate (C) and incommensurate (IC) regimes. S(23D) and L(3D) are the bulk solid and hquid phases. Sohd lines denote first-order transitions and dashed lines denote continuous transitions.

Fig. XVII-17. Schematic phase diagram for O2 on graphite (see text). (From Ref 95. Reprinted with permission from American Chemical Society, copyright 1996.)...

Fig. 1. Carbon-phase diagram where A, solvent-cataly2ed diamond growth B—G, diamond formation direcdy from graphite C, graphite formation from diamond, D, approximate region where formation of Lonsdaleite occurs from weU-ordered graphite crystals (7,8). To convert GPa to atm, multiply by...

Figure 6.3 The iron-carbon phase diagram showing the alternative production of iron and cementite from the liquid alloy, which occurs in practice, to the equilibrium production of graphite...

Phase transitions in two-dimensional layers often have very interesting and surprising features. The phase diagram of the multicomponent Widom-Rowhnson model with purely repulsive interactions contains a nontrivial phase where only one of the sublattices is preferentially occupied. Fluids and molecules adsorbed on substrate surfaces often have phase transitions at low temperatures where quantum effects have to be considered. Examples are molecular layers of H2, D2, N2 and CO molecules on graphite substrates. We review the path integral Monte Carlo (PIMC) approach to such phenomena, clarify certain experimentally observed anomalies in H2 and D2 layers, and give predictions for the order of the N2 herringbone transition. Dynamical quantum phenomena in fluids are analyzed via PIMC as well. Comparisons with the results of approximate analytical theories demonstrate the importance of the PIMC approach to phase transitions where quantum effects play a role. 

Cast irons, although common, are in fact quite complex alloys. The iron-carbon phase diagram exhibits a eutectic reaction at 1 420 K and 4-3 wt.<7oC see Fig. 20.44). One product of this eutectic reaction is always austenite however, depending on the cooling rate and the composition of the alloy, the other product may be cementite or graphite. The graphite may be in the form of flakes which are all interconnected (although they appear separate on a... 

The phase diagram for carbon, shown here, indicates the extreme conditions that are needed to form diamonds front graphite, (a) At 2000 K, what is the minimum pressure needed before graphite changes into diamond (b) What is the minimum temperature at which liquid carhon can exist... 

Use the phase diagram for carbon in Exercise 8.14 (a) to describe the phase transitions that carbon would undergo if compressed at a constant temperature of 2000 K from 100 atm to 1 X 106 atm (b) to rank the diamond, graphite, and liquid phases of carbon in order of increasing density. 

Figure 5.4 The phase diagram of carbon showing the two solid-state extremes of diamond and graphite. Graphite is the thermodynamically stable form of carbon at room temperature and pressure, but the rate of the transition C iamond) — C aphite) is virtually infinitesimal...

Figure 5.29. Fe-rich region of the Fe C phase diagram. Stable Fe-C (graphite) diagram solid lines metastable Fe-Fe3C diagram dashed lines. The following current names are used ferrite (solid solution in aFe), austenite (solid solution in 7Fe) and cementite (Fe3C compound). Pearlite is the name given to the two-phase microstructure which originates from the eutectoid reaction ...

Figure lU. Calculated metastable Fe-C phase diagram. Stable diagram with graphite is shown by dotted lines (Gustafson 1985). 

Figure 4.14. Phase diagram, coverage vs. temperature, of N2 physisorbed on graphite. Symbols used fluid without any positional or orientational order (F), reentrant fluid (RF), commensurate orientationally disordered solid (CD), commensurate herringbone ordered solid (HB), uniaxial incommensurate orientation-ally ordered (UlO) and disordered (UID) solid, triangular incommensurate orientationally ordered (lO) and disordered (ID) solid, second-layer liquid (2L), second-layer vapour (2V), second-layer fluid (2F), bilayer orientationally ordered (2SO) and disordered (2SD) solid. Solid lines are based on experimental results whereas the dashed lines are speculative. Adapted from Marx Wiechert, 1996.

The importance of solvents and their effects play roles in electrochemistry as well. The properties of a family of novel quaternary ammonium salts based on the bis(triflu-oromethylsulfonyl)imide and triflate anions are reported in a paper by Sun (Sun et al., 1998). Binary phase diagrams for some of their mixtures and their electrochemical windows of stability were reported. The highest conductivity observed in the pure salt systems at 25°C was 7 x 10 S cm-1. An electrochemical window of stability of up to 5V was measured on graphite electrodes. The effect of salt structure and solvent on conductivity of the salts is also discussed. 

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