Goshe

Chloro-7-nitrobenzofurazane (7-chloro-4-nitrobenzoxadiazole) [10199-89-0] M 199.6, m 96.5-97°, 97°, 99-100°. Wash the solid with H2O and recrystallise from aqueous EtOH (1 1) as pale yellow needles. It sublimes in a vacuum [UV, NMR Bolton, Gosh and Katritzky J Chem Soc 1004 1966]. 

Aminoacids are starting materials for the preparation of compounds (41) with 0x0 groups in the G-position. The reaction described by Gosh can serve as an example ... 

Goshe, A.J., Steele, I.M., Ceccarelli, C., Rheingold, A.L. and Bosnich, B. (2002) Supramolecular chemistry and self-assembly special feature supramolecular recognition on the kinetic lability of thermodynamically stable host-guest association complexes. Proceedings of the... 

Gosh et al. reported LDA(SVWN) studies of oxo(porphyrinato)iron(IV) complexes.83 These compounds have been detected in various peroxidases and are believed to be involved in the reaction mechanisms of other heme enzymes, such as cytochromes P450. Very Good Fe-0 distance and values of unsealed stretching frequencies, which were in excellent agreement with CASSCF results, published elsewhere, were obtained. 

Gosh, A., J. Almlof, and L. Que Jr. 1994. Density Functional Theoretical Study of Oxo(porphyroinato)iron(IV) Complexes, Models of Peroxidase Compounds I and II. J. Phys. Chem. 98, 5576. 

Samanta, A. A., and S. K. Gosh. 1995. Density functional approach to the solvent effects on the dynamics of nonadiabatic electron transfer reactions. J. Chem. Phys. 102, 3172. 

Goshe M.B., Anderson V.E. Hydroxyl radical-induced hydrogen/ deuterium exchange in amino acid carbon-... 

A generalization of Harriman s orbitals has been proposed by Gosh and Parr [63] it is based on a description similar to that of Zumbach and Maschke [61] but uses polar spherical coordinates ... 

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