Gallium complex

Consequently, due to preferred cis-cis orientation a dimeric structure is observed for the indium complex and an unprecedented cis-trans arrangement in the thallium structure leads to a polymeric aggregate. Further N-NMR spectroscopic studies show that the aluminum and gallium complexes are stable contact ion pairs even in solution whereas the indium and thallium compounds are solvent-separated ion pairs in THE solution. 

Indium and gallium coordination compounds containing phosphine ligands have recently aroused interest for their widespread application as intermediates in the preparation of the Group 13 - Group 14 semiconductors [4], Since the early reports about compounds with transition metal-indium bonds [51, relatively little research has been reported in this field. However there is a growing interest in the coordination chemistry and structural features of heterometallic indium [6] and gallium complexes [7] which are also attractive as potential precursors of new materials with particular properties. 

J. Qiao, Y. Qiu, L. Wang, L. Duan, Y. Li, and D. Zhang, Pure red electroluminescence from a host material of binuclear gallium complex, Appl. Phys. Lett., 81 4913 1915 (2002). 

Shibasaki and coworkers have applied heterobimetalhc gallium complexes to the desymmetrization of meso epoxides using phenolic nucleophiles. Complex 35 is... 

Elhabiri, M. et al., Anthocyanin-aluminium and -gallium complexes in aqueous solution, J. Chem. Soc., Perkin Trans. 2, 355, 1997. 

Gallium alkoxides physical properties, 345 Gallium complexes dimethyl sulfoxide, 488 phthalocyanines, 863 porphyrins, 821 Gallium(III) complexes porphyrins evolution, 961 tropolones rearrangement, 382 Gallium isopropoxides synthesis... 

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