Gallium complexes nitrates

Corroles are tetrapyrrole macrocycles that are closely related to porphyrins, with one carbon atom less in the outer periphery and one NH proton more in their inner core. They may also be considered as the aromatic version (identical skeleton) of the only partially conjugated corrin, the cobalt-coordinating ligand in Vitamin B12. Two potential application of corroles are in tumor detection and their use in photovoltaic devices. Selective substitution of corroles via nitration, hydroformylation, and chlorosulfonation for the gallium were studied in detail and the respective mechanistic pathways and spectroscopic data were reported, (an example is shown in Figure 27). Overall, over 139 various corroles were synthesized and the effect of various metal complexation pertaining to their selective reactivity examined. 

Gallium(III) complexes, 129 amines, 129 amino acids, 141 arsenates, 135 borates, 134 borohydrides, 141 bromates, 135 carbonates, 134 caiboxylates, 135 chlorates, 135 citrates, 136 cyanides, 129 dithiocarbamates, 138 ethers, 136 fluorides, 138 germanates, 134 hydrides, 140 iodates, 135 p-ketoenolates, 134 lactates, 136 mixed halides, 139 molybdates, 135 nitrates, 135 peptides, 141 perchlorates, 135... 

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