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Frank factor

For bound state systems, eigenfunctions of the nuclear Hamiltonian can be found by diagonalization of the Hamiltonian matiix in Eq. (11). These functions are the possible nuclear states of the system, that is, the vibrational states. If these states are used as a basis set, the wave function after excitation is a superposition of these vibrational states, with expansion coefficients given by the Frank-Condon overlaps. In this picture, the dynamics in Figure 4 can be described by the time evolution of these expansion coefficients, a simple phase factor. The periodic motion in coordinate space is thus related to a discrete spectrum in energy space. [Pg.264]

The F factor correlation from Frank is shown in Figure... [Pg.60]

Workforce Support for Data Collection and Incident Analysis Systems Few of the incident investigation and data collection systems reviewed provide any guidelines with regard to how these systems are to be introduced into an organization. Section 6.10 addresses this issue primarily from the perspective of incident reporting systems. However, gaining the support and ownership of the workforce is equally important for root cause analysis systems. Unless the culture and climate in a plant is such that personnel can be frank about the errors that may have contributed to an incident, and the factors which influenced these errors, then it is unlikely that the investigation will be very effective. [Pg.288]

Wadden RA, Scheff PA, Franke JE. 1989. Emission factors for trichloroethylene vapor degreasers. Am Ind Hyg Assoc J 50 496-500. [Pg.295]

B.G.M. Vandeginste, F. Leyten, M. Gerritsen, J.W. Noor, G. Kateman and J. Frank, Evaluation of curve resolution and iterative target transformation factor analysis in quantitative analysis by liquid chromatography. J. Chemom., 1 (1987) 57-71. [Pg.304]

A common practice is to calculate the pressure drop using the methods for single-phase flow and apply a factor to allow for the change in vapour velocity. For total condensation, Frank (1978) suggests taking the pressure drop as 40 per cent of the value based on the inlet vapour conditions Kern (1950) suggests a factor of 50 per cent. [Pg.723]

The rate constants for these relatively short range hole transfer reactions generally decrease exponentially with distance. Yet, characterizing these DNA-mediated reactions with the parameter (3 is a simplification and is certainly inappropriate in cases where the Frank-Condon factor varies with distance (such as has been observed for the acridine photooxidant). Keeping these limitations in mind, however, /i-values for DNA-mediated hole transfer of -0.6-0.7 A-1 have been suggested using several different oxidant-DNA assemblies (Ap, St, Ap radical cation). [Pg.115]

The factor rotation by which the factors are transformed into more interpretable variables and can be tested concerning hypothetical data structures, respectively. There are various techniques of factor rotation with specific advantages in several fields of application (Frank and... [Pg.266]

In the quantum mechanical formulation of electron transfer (Atkins, 1984 Closs et al, 1986) as a radiationless transition, the rate of ET is described as the product of the electronic coupling term J2 and the Frank-Condon factor FC, which is weighted with the Boltzmann population of the vibrational energy levels. But Marcus and Sutin (1985) have pointed out that, in the high-temperature limit, this treatment yields the semiclassical expression (9). [Pg.20]

Duarte, R. and Frank, D. 2002. The synergy between stem cell factor (SCF) and granulocyte colony stimulating factor (G-CSF) molecular basis and clinical relevance. Leukaemia and Lymphoma 43(6), 1179-1187. [Pg.288]

Critical heat production rates (i.e., heat production rates that still do not lead to a runaway), are often determined by small scale experiments. However, the effect of scale-up on these rates, as discussed in [161], must be taken into account. An indication of the effect of scaling in an unstirred system is shown in Figure 3.2. In this figure, the heat production rate (logarithmic scale) is shown as a function of the reciprocal temperature. Point A in the figure represents critical conditions (equivalent heat generation and heat removal) obtained in a 200 cm3 Dewar vessel set-up. It can be calculated from the Frank-Kamenetskii theory on heat accumulation [157, 162] that the critical conditions are lowered by a factor of about 12 for a 200 liter insulated drum. These conditions are represented by... [Pg.94]

The second model, proposed by Frank-Kamenetskii [162], applies to cases of solids and unstirred liquids. This model is often used for liquids in storage. Here, it is assumed that heat is lost by conduction through the material to tire walls (at ambient temperature) where the heat loss is infinite compared to the rate of heat conduction through the material. The thermal conductivity of the material is an important factor for calculations using this model. Shape is also important in this model and different factors are used for slabs, spheres, and cylinders. Case B in Figure 3.20 indicates a typical temperature distribution by the Frank-Kamenetskii model, showing a temperature maximum in the center of the material. [Pg.143]

Fleming, A., Corter, C., Surbey, M., Franks, P. and Steiner, M. (1995) Postpartum factors related to mother s recognition of newborn infant odours. J. Reprod. Infant. Psyc. 13, 197-210. Gower, D.B., Bird, S., Sharma, P. and House, F.R. (1985) Axillary 5 alpha-androst-16-en-3-one in men and women relationship with olfactory acuity to odorous 16-androstenes. Experientia 41, 1134-1136. [Pg.197]

B13. Baker, H., Leevy, C. M., and Frank, O., An alkali resistant factor with B12-like activity for protozoa and man. In press. [Pg.240]


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