Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Fourier number, critical

TABLE 3.8 Asymptotic Values of First Eigenvalues, Correlation Parameter n, and Critical Fourier Number... [Pg.154]

Fourier number based on square root of area critical value of Fourier number radiative parameter for point contact elastoplastic contact parameter gap conductance correlation equation metric coefficients, jacobian height of single and double cones Rockwell C hardness number Brinell hardness... [Pg.190]

Non-uniform temperature distribution in a reactor assumed model based on the Fourier heat conduction in an isotropic medium equality of temperatures of the medium and the surroundings assumed at the boundary critical values of Frank-Kamenetskii number given. [Pg.378]

The critical nucleus of a new phase (Gibbs) is an activated complex (a transitory state) of a system. The motion of the system across the transitory state is the result of fluctuations and has the character of Brownian motion, in accordance with Kramers theory, and in contrast to the inertial motion in Eyring s theory of chemical reactions. The relationship between the rate (probability) of the direct and reverse processes—the growth and the decrease of the nucleus—is determined from the condition of steadiness of the equilibrium distribution, which leads to an equation of the Fourier-Fick type (heat conduction or diffusion) in a rod of variable cross-section or in a stream of variable velocity. The magnitude of the diffusion coefficient is established by comparison with the macroscopic kinetics of the change of nuclei, which does not consider fluctuations (cf. Einstein s application of Stokes law to diffusion). The steady rate of nucleus formation is calculated (the number of nuclei per cubic centimeter per second for a given supersaturation). For condensation of a vapor, the results do not differ from those of Volmer. [Pg.120]

The position of ZPD (Zero Path Difference) is critical to the Fourier Transform calculation, since the algorithm assumes that the central burst in the interferogram is in fact the ZPD. However, due to the refractive index properties of the beamsplitter material, the ZPD is not at the same position for every wavelength measured. There are several ways to overcome these phase differences. The most common method is to use a correction factor, which is known as phase correction. This correction factor is calculated for every wavelength, based on a double sided interferogram, since this tends to minimize the effects of phase difference. In practice, most infrared spectrometers collect single sided interferograms, since this halves the mirror movement, and consequently the number of datapoints to be Fourier transformed. [Pg.495]

This three-dimensional electron-density distribution is represented by a series of parallel sections stacked on top of one another. Each section is a transparent plastic sheet or, more recently, a layer in a computer image) on which the electron-density distribution is represented by contour lines (Figure 3.45), like the contour lines used in geological survey maps to depict altitude (Figure 3.46). The next step) is to interpret the electron-density map. A critical factor is the resolution of the x-ray analysis, which is determined by the number of scattered intensitie.s used in the Fourier synthesis. The fidelity of the image... [Pg.96]

Several different experimental techniques, such as fluorescence decay, electron spin resonance (ESR) spectroscopy, Raman spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, neutron reflectome-try, calorimetry, Fourier-transform infrared (FT-IR) adsorption spectroscopy, small-angle neutron scattering (SANS), ellipsometry and surface force measurements, have been used to study self-assembled surfactant structures at the solid-liquid interface (11). These measurements, although providing insight into the hemimicellization process, critical aggregation numbers... [Pg.237]

To describe mathematically the process of thin liquid film instability the shape of the corrugated film surfaces is presented as a superposition of Fourier-Bessel modes, proportional to Jo(kr/R), for all possible values of the dimensionless wave number k (Jo is the zeroth order Bessel function). The mode, which has the greatest amplitude at the moment of film breakage, and which causes the breakage itself, is called the critical mode, and its wave number is denoted by cr- The stability-instability transition for this critical mode happens at an earlier stage of the film evolution, when the film thickness is equal to Atr - the so-called transitional thickness, h r > her (Ivanov 1980). The theory provides a... [Pg.30]

The upper value of n corresponds exactly to the critical sampling frequency of two sample points per cycle (i.e., the Nyquist critical frequency). Thus, in general, the discrete Fourier transform maps N complex numbers into N/2 complex numbers [75],... [Pg.473]

Several review papers discuss the preparation, characterization, properties, and applications of bio-nanocomposites (Pandey et al., 2005 Ray and Bousmina, 2005 Yang et al, 2007 Rhim and Ng, 2007 Sorrentino et al., 2007 Zhao et al., 2008 Bordes et al., 2009). However, there is a lack of comprehensive review on various analytical techniques for the stmctural characterization of bio-nanocomposites. Selection of proper technique for characterization of these bio-nanocomposites is very critical in assessing their performance. A number of analytical techniques have been used to characterize the stracture of bio-nanocomposites. These techniques include X-ray diffraction (XRD), microscopy transmission electron microscope (TEM), scanning electron microscope (SEM), scanning probe microscope (SPM), and confocal scanning laser microscope (CSLM), Fourier transform infra-red (FTIR) spectroscopy, and nuclear magnetic resonance (NMR). Each of the above mentioned techniques has its own benefits and limitations. [Pg.309]


See other pages where Fourier number, critical is mentioned: [Pg.6]    [Pg.692]    [Pg.154]    [Pg.154]    [Pg.702]    [Pg.484]    [Pg.464]    [Pg.24]    [Pg.24]    [Pg.137]    [Pg.5]    [Pg.672]    [Pg.203]    [Pg.711]    [Pg.6385]    [Pg.270]    [Pg.178]    [Pg.384]    [Pg.214]    [Pg.111]    [Pg.361]    [Pg.305]    [Pg.6384]    [Pg.186]    [Pg.456]    [Pg.42]    [Pg.2106]    [Pg.344]    [Pg.258]    [Pg.134]    [Pg.709]    [Pg.364]    [Pg.632]    [Pg.29]   
See also in sourсe #XX -- [ Pg.3 , Pg.25 ]




SEARCH



Number critical

© 2024 chempedia.info