Formation of Precipitates

The function of pH adjustment is to neutralize acids and bases and to promote the formation of precipitates (especially of heavy metal precipitates) which can subsequently be removed by conventional settling techniques. These purposes are not mutually exclusive, precipitates can be formed as the result of neutralizing a waste. Conversely, neutralization of the waste stream can result when adjusting the pH to effect chemical precipitation. Typically, pH adjustment is effective in treating inorganic or... 

The mass transfer effect is relevant when the chemical reaction is far faster than the molecular diffusion, i.e. Ha > 1. The rapid formation of precipitate particles should then occur spatially distributed. The relative rate of particle formation to chemical reaction and/or diffusion can as yet be evaluated only via lengthy calculations. 

Tris(2-aminoethyl)amine, CH2CI2. This amine acts as the deblocking agent and the scavenger for the dibenzofulvene and does not cause the formation of precipitates or emulsions, which sometimes occur. ... 

Figure 12.13. Image depicting the formation of precipitates, seen as small dark spots, in a palladium precursor solution after 1 day of storage. The image shown was taken of a drop of precursor solution that was dispensed onto a microscope slide and covered with a glass cover slide.

Apart from these, there are volume defects that cannot conveniently be described in any other terms. The most important of these consist of regions of an impurity phase—precipitates—in the matrix of a material (Fig. 3.39). Precipitates form in a variety of circumstances. Phases that are stable at high temperatures may not be stable at low temperatures, and decreasing the temperature slowly will frequently lead to the formation of precipitates of a new crystal structure within the matrix of the old. Glasses, for example, are inherently unstable, and a glass may slowly recrystallize. In this case precipitates of crystalline material will appear in the noncrystalline matrix. 

The solution is stirred slowly and ca. 25 ml. of 2N cupric chloride solution is added slowly. The blue-green color of the cupric chloride is rapidly discharged and a brick red coloration occurs, followed by the precipitation of voluminous bright red crystals of the cuprous chelate of 2,3-diazabicyclo[2.2.1]hept-2-ene. The pH is adjusted to 5-6 by the addition of 5N ammonium hydroxide. Addition of 25 ml. of the cupric chloride solution followed by neutralization of the generated hydrochloric acid with 5iV ammonium hydroxide is repeated five times. The precipitate is collected by filtration and the filtrate is again treated with 25-ml. portions of cupric chloride solution and 5N ammonium hydroxide. The procedure is repeated until the filtrate is clear red at pH 3-4 and returns to a cloudy green at pH 6 with no further formation of precipitate (Note 5). 

The water vapor available in the air plays a decisive part in the formation of precipitation. The amount of water that can be retained in the air in the form of vapor is primarily dependent on the temperature Warm air masses can absorb more humidity than cold air masses, whereby there is an exponential correlation between temperature and saturation humidity (Fig. 1, [4]). 

Process of contact and adhesion whereby dispersed particles are held together by weak physical interactions ultimately leading to phase separation by the formation of precipitates of larger than colloidal size. 

By addition of up to 80% (v/v) of organic solvents such as methanol, ethanol, or acetone to protein solutions, a formation of precipitates occurs. Varying the solvent concentration allows a fractionation as described for salting out. Because organic solvents tend to denature proteins at temperatures above 10 °C, precipitation and all further steps have to be performed at 0 °C or below. Some buffer salts may precipitate also at elevated concentrations of organic solvents therefore, the ionic strength of buffers should not be above 0.2. 

The histological findings after 3 months treatment show lesser damages of the tissues as in case of PFCLs, but inflammatory effects, the formation of precipitates and a distinctive emulsification are non-tolerable side effects [28,29] (Table 3). 

Oral Solutions and Suspensions Formation of precipitate, clarity for solutions, pH, viscosity, microbial bioburden, extractables, and polymorphic conversion when applicable. Additional tests for suspensions include redispersability, rheological properties, mean size, and distribution of particles. 

Explain the formation of precipitates using the concept of the solubility product (see Appendix 1, Table 12). In what cases was no precipitate formed when the salts were poured together ... 

Tab. 2.8 Solvent effects on the formation of precipitates and complexes of the silver ion with halide ions (X-)...

Whatever theoretical explanation of the chelate effect is adopted, there is no doubt as to the extra stability conferred by polydentate ligands capable of forming one or more chelate rings. This is of especial importance in titrimetry (see Section 10.6) and, as we shall see shortly, bidentate ligands play a significant role in the formation of precipitates of value in gravimetry. 

All activity values are extrapolated to the levels expected for 5 mug of enzyme. The concentrations of substrate and cation listed are those affording maximal activity without formation of precipitate. 

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