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Fluoroformyl

Fluoroformyl peroxide [692-74-0] (20, R = R = F), has been prepared by the reaction of carbon monoxide, fluorine, and oxygen or by the photolytic reaction of oxalyl fluoride with oxygen (187). [Pg.125]

The experimental 13C NMR chemical shift of the simplest member of the acylium ions, the formyl cation [HCO]+ was reported as S = 139.5 (measured under CO pressure of 85 atm) which compares well with the GIAO-MP2 calculated shift of S — 136ppm.116,117 The analogous fluoroformyl cation [FCO]+ and protonated fluoroformic acid [FC(OH)2]+ were characterized by 13C NMR spectroscopy, experimentally118 ((5=117.5 and 157.8 ppm, respectively) as well as computationally (S = 118.6 and 170.6ppm, respectively).119... [Pg.156]

In addition to carbon dioxide, small amounts of fluoroformyl fluoride and chloride are formed and swept out with the carbon dioxide. [Pg.146]

Reactions that have led to other deoxyhalogeno sugars do not necessarily lead to deoxyfluoro sugars, as, for example, in the attempted decomposition of fluoroformates, the treatment of diazoketones and of 2-deoxy-2-diazohexonates with hydrogen fluoride, and the reaction of benzoxonium ions with halide ions. The reaction2281229 by which fluoroformates are thermally or catalytically decarbonylated to give alkyl fluorides has been applied to carbohydrates. Both thermal and catalytic treatment of 6-0-(fluoroformyl)-l,2 3,4-di-0-isopropylidene-... [Pg.242]

Bis(fluoroformyl) peroxide, 0625 Bis-3-(2-furyl)acryloyl peroxide, 3640 Bis(trichloroacetyl) peroxide, 1361 Bis(trifluoroacetyl) peroxide, 1367 Diacetyl peroxide, 1537 Dibenzenesulfonyl peroxide, 3499 Dibenzoyl peroxide, 3639 Di-3-camphoroyl peroxide, 3807 Dicrotonoyl peroxide, 2986 Dicyclohexylcarbonyl peroxide, 3667 Didodecanoyl peroxide, 3857 Di-2-furoyl peroxide, 3245 Dihexanoyl peroxide, 3554 Diisobutyryl peroxide, 3032 Diisopropyl peroxydicarbonate, 3034 Dimethanesulfonyl peroxide, 0931 Di-2-methylbutyryl peroxide, 3354 Di-l-naphthoyl peroxide, 3831 3,6-Dioxo-l,2-dioxane, 1445 Dipropionyl peroxide, 2442 Dipropyl peroxydicarbonate, 3035 Di-4-toluenesulfonyl peroxide, 3656 Peroxodisulfuryl difluoride, 4328 Phthaloyl peroxide, 2900 Potassium benzenesulfonylperoxosulfate, 2257 Potassium O-O-benzoylmonoperoxosulfate, 2684 (9-TriIIuoroacctyl-.S -lluorofonny 1 thioperoxide, 1050 See PEROXIDES, PEROXYCARBONATE ESTERS... [Pg.109]

Synonyms carbon oxyfluoride carbonyl difluoride fluoroformyl fluoride flu-orophosgene... [Pg.196]

Fluorocarbonyl peroxynitrate gas electron diffraction, 744 NMR spectroscopy, 743 vibrational spectmm, 743 Fluoroethylenes, final ozonide, 722 Fluoroformyl peroxide, conformation, 702 Fluorometry... [Pg.1462]

Trifluoroacetyl peroxide, stmcture, 702-3 Trifluoroacetyl peroxynitrate, IR spectrum, 743 Trifluoromethyl fluoroformyl peroxycarbonate photochemical synthesis, 740 vibrational spectra, 705 Trifluoromethyl peroxynitrate, UV spectroscopy, 743... [Pg.1494]

Fluoroformyl Fluoride. See Carbonyl Fluoride in this Section... [Pg.522]

Trifluoromethyl, fluoroformyl, and trifluoroacetyl isocyanates87 as well as A-haloimines88 easily add chlorine monofluoride to the C = N bonds. [Pg.250]

Fluoroformyl)phenyl Trifluoromethyl Ether Typical Procedure 83 8 ... [Pg.519]

One example of a fluoroformyl complex 46 has been prepared by the reaction of XeF2 with [Ir(CO)3(PEt3)2]+ (114). Some routes to perfluorovinyl... [Pg.200]

Acyl Halides. Acyl halides, in which the hydroxyl portion of a carboxyl group is replaced by a halogen, are named by placing the name of the corresponding halide after that of the acyl radical. When another group is present that has priority for citation as principal group or when the acyl halide is attached to a side chain, the prefix haloformyl- is used as, for example, in fluoroformyl-. [Pg.26]

Af-Trifluoroacetoxy-2,4-dinitroaniline, 2887 Trifluoroacetyl azide, 0623 2-Trifluoroacetyl-1,3,4-dioxazalone, 1044 0-Trifluoroacetyl-5-fluoroformyl thioperoxide, 1047 Trifluoroacetyl hypochlorite, 0591 Trifluoroacetyl hypofluorite, 0629 Trifluoroacetyhminoiodobenzene, 2898 Trifluoroacetyl nitrite, 0622 Trifluoroacetyl trifluoromethanesulfonate, 1054 Trifluoroacryloyl fluoride, 1046... [Pg.2149]

Acetyl cyclohexanesulfonyl peroxide, 3028 2,2 -Biphenyldicarbonyl peroxide, 3624 Bis(2,4-dichlorobenzoyl) peroxide, 3617 Bis(2-azidobenzoyl) peroxide, 3621 Bis(3,4-dichlorobenzenesulfonyl) peroxide, 3439 Bis-3-(2-furyl)acryloyl peroxide, 3633 Bis(3-carboxypropionyl) peroxide, 2985 Bis(4-chlorobenzenesulfonyl) peroxide, 3452 Bis(bromobenzenesulfonyl) peroxide, 3447 Bis(fluoroformyl) peroxide, 0621 Bis(trichloroacetyl) peroxide, 1357 Bis(trifluoroacetyl) peroxide, 1363 Di-1-naphthoyl peroxide, 3825 Di-2-furoyl peroxide, 3239 Di-2-methylbutyryl peroxide, 3348 Di-3-camphoroyl peroxide, 3801 Di-4-toluenesulfonyl peroxide, 3649 Diacetyl peroxide, 1532 Dibenzenesulfonyl peroxide, 3493 Dibenzoyl peroxide, 3632 Dicrotonoyl peroxide, 2981 Dicyclohexylcarbonyl peroxide, 3660 Didodecanoyl peroxide, 3851 Dihexanoyl peroxide, 3548 Diisobutyryl peroxide, 3027 Diisopropyl peroxydicarbonate, 3029 Dimethanesulfonyl peroxide, 0927 3,6-Dioxo-l,2-dioxane, 1441... [Pg.2295]

Dipropionyl peroxide, 2436 Dipropyl peroxydicarbonate, 3030 Peroxodisulfuryl difluoride, 4322 Phthaloyl peroxide, 2895 Potassium benzenesulfonylperoxosulfate, 2250 Potassium O—O-benzoylmonoperoxosulfate, 2680 O-Trifluoroacetyl-S -fluoroformyl thioperoxide, 1047 See PEROXIDES, PEROXYCARBONATE ESTERS... [Pg.2296]

See other pages where Fluoroformyl is mentioned: [Pg.69]    [Pg.413]    [Pg.298]    [Pg.110]    [Pg.219]    [Pg.243]    [Pg.386]    [Pg.1518]    [Pg.659]    [Pg.53]    [Pg.73]    [Pg.372]    [Pg.702]    [Pg.705]    [Pg.740]    [Pg.511]    [Pg.702]    [Pg.705]    [Pg.740]    [Pg.413]    [Pg.243]    [Pg.269]    [Pg.432]    [Pg.1579]   
See also in sourсe #XX -- [ Pg.99 , Pg.144 ]



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Fluoroformyl fluoride

Fluoroformyl radicals

Trifluoromethyl fluoroformyl peroxycarbonate

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