Trifluoromethyl peroxynitrate

The UV absorption spectrum of gaseous trifluoromethyl peroxynitrate (1) shows a continuous decrease of intensity from 185 nm to 340 nm. The reported absorption cross section (a/10 ° cm ) ranges from 370 at 190 nm, to 1.0 at 290 nm and to 0.014 at 340 nm. Using published solar flux data in the troposphere at sea level, and assuming a unity quantum yield, a half-life time of about 1 month can be estimated for compound 1, which makes it a potentially effective carrier of pollutants from industrial zones to remote unpolluted sites . ... 

Trifluoroacetyl peroxide, stmcture, 702-3 Trifluoroacetyl peroxynitrate, IR spectrum, 743 Trifluoromethyl fluoroformyl peroxycarbonate photochemical synthesis, 740 vibrational spectra, 705 Trifluoromethyl peroxynitrate, UV spectroscopy, 743... 

Triterpenes, structural chemistry, 136 Tropopause, emissions model, 605 Troposphere ozone analysis, 605 trifluoromethyl peroxynitrate, 743 Tryptophan... 

Trifluoromethyl peroxynitrate, CF300N02, has been obtained in high yield by the reaction of CF3OOH with N2Os or CF3OOF with N204.132 Its... 

Trifluoromethyl peroxynitrate, CF300N02, has been synthesized from the reaction of trifluoromethyl hydroperoxide with N2Os or of fluoroperoxy-trifluoromethane with N204. The vibrational spectrum was assigned based on a molecule of Cs symmetry.155... 

Hohorst F.A. and D.D. DesMarteau Some reactions of CF3OO derivatives with inorganic nitrogen compounds. Synthesis and vibrational spectrum of trifluoromethyl peroxynitrate,/norg. Chem. 13 (1974) 715-719. 

Kopitzky R., H. Willner, H.-Q. Mack, A. Pfeiffer and H. Oberhammer IR and UV absorption cross sections, vibrational analysis, and the molecular strueture of trifluoromethyl peroxynitrate, CF3OONO2, Inorg. Chem. 37 (1998) 6208-6213. 

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