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Fluoroformic acid

The experimental 13C NMR chemical shift of the simplest member of the acylium ions, the formyl cation [HCO]+ was reported as S = 139.5 (measured under CO pressure of 85 atm) which compares well with the GIAO-MP2 calculated shift of S — 136ppm.116,117 The analogous fluoroformyl cation [FCO]+ and protonated fluoroformic acid [FC(OH)2]+ were characterized by 13C NMR spectroscopy, experimentally118 ((5=117.5 and 157.8 ppm, respectively) as well as computationally (S = 118.6 and 170.6ppm, respectively).119... [Pg.156]

Further -oxidation of this acid would give the unknown fluoroformic acid, F -COOH, which would of course immediately decompose to give CO and HF, which would be non-toxic at the concentrations employed. [Pg.166]

Fluorides from fluoroformic acid esters OGOF F... [Pg.439]

Carbonofluoridic acid methyl ester Fluoroformic acid methyl ester... [Pg.674]

Difluoroborinic acid esters Fluoroformic acid esters... [Pg.306]

See other pages where Fluoroformic acid is mentioned: [Pg.22]    [Pg.372]    [Pg.1568]    [Pg.97]    [Pg.212]    [Pg.96]    [Pg.190]    [Pg.296]    [Pg.306]    [Pg.312]    [Pg.537]    [Pg.316]    [Pg.261]    [Pg.261]    [Pg.261]   
See also in sourсe #XX -- [ Pg.97 ]



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Fluoroformates

Fluoroformic acid esters

Fluoroformic acid esters fluoroformates)

Fluoroformic acid, methyl ester

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