Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Fixed energy

If the network is optimized at fixed energy consumption, then only loops and stream splits are used. When energy consumption is allowed to vary, utility paths also must he included. As the network energy consumption increases, the overall capital cost decreases. [Pg.394]

This equation represents the reaction rate at total energy E with a fixed energy in the reaction coordinate and may be written as... [Pg.1012]

Unfortunately, in the VUV region no polarimetry data are available, but calculations indicate the degree of circular polarization achieved by the wiggler may be 80%, estimated to be no worse than 70% delivered at the experimental chamber [95, 96]. In PECD experiments, we have calibrated the polarization state by deduction from cross-comparison of results at a few fixed energies previously studied on the SU5 beamline where accurate polarimetry data was available [36]. Because the horizontal magnetic field array in the insertion device is electromagnetic, fast current reversal to switch left- and right-handed elliptical polarizations is possible, with the usual potential benefit for dichroism measurements. [Pg.303]

The K-matrix method is essentially a configuration interaction (Cl) performed at a fixed energy lying in the continuum upon a basis of "unperturbed funetions that (at the formal level) includes both diserete and eontinuous subsets. It turns the Schrodinger equation into a system of integral equations for the K-matrix elements, which is then transformed into a linear system by a quadrature upon afinite L basis set. [Pg.368]

Consider N fermions in a box with fixed energy levels E, (including rest-mass which itself includes internal excitation energy). To each E, there correspond co, distinct (degenerate) states, made up of gi internal states and 4n Vp2dp/h3 kinetic degrees of freedom, where p is momentum and V is the volume. [Pg.28]

Another way of looking at the Boltzmann distribution assumes that the energy spectrum consists of closely spaced, but fixed energy levels, e . The probability that level u is populated is specified in terms of the canonical distribution... [Pg.449]

And each photon has a fixed energy E. We say the energy is quantized. The intensity of a beam of light is merely a function of the number of photons within it per unit time see below. [Pg.433]

For many of the analytical techniques discussed below, it is necessary to have a source of X-rays. There are three ways in which X-rays can be produced in an X-ray tube, by using a radioactive source, or by the use of synchrotron radiation (see Section 12.6). Radioactive sources consist of a radioactive element or compound which spontaneously produces X-rays of fixed energy, depending on the decay process characteristic of the radioactive material (see Section 10.3). Nuclear processes such as electron capture can result in X-ray (or y ray) emission. Thus many radioactive isotopes produce electromagnetic radiation in the X-ray region of the spectrum, for example 3He, 241Am, and 57Co. These sources tend to produce pure X-ray spectra (without the continuous radiation), but are of low intensity. They can be used as a source in portable X-ray devices, but can be hazardous to handle because they cannot be switched off. In contrast, synchrotron radiation provides an... [Pg.99]

The density of states for a transition state depends upon the non-fixed energy minus the critical energy. Taking the critical energy for the central transition state as an adjustable parameter, we can calculate efficiencies until we find a match with experiment. We have already demonstrated that our calculations for the decomposition transition state (k ), using... [Pg.91]

Figure 4 (a) Scattered electron intensity at fixed energy loss A = 0.25 eV as a function of incident electron energy at several angles of incidence 6q on a 50-ML (monolayers) Ar film, (b) CB DOS for fee structure of solid Ar as calculated by Bacalis et al. [88]. (From Ref. 83.)... [Pg.216]

So the A potential—in either of its components AL or Ac—is not to be thought of as having fixed energy since it consists of and identically is a myriad energy flow processes ongoing between the time-energy domain (the complex plane) and the real energy domain (real 3-space). [Pg.725]

Here the average is over all states separated by a fixed energy difference hcom and N0(Ef) is the density of states per spin. This formula has been derived by various methods (MacMilliah 1981, Kaveh and Mott 198 la, b, Imry et a/. 1982, Lee 1982). For non-zero q, we find, making o>->0, as in the derivation of the Kubo-Greenwood formula (34),... [Pg.48]

The second idea related to the LEED technique is, as its name indicates, the diffraction phenomenon. With the wave nature of the electrons established, information on the interaction of a beam of light with matter can be extrapolated to understand the interaction of a beam of electrons with a crystal. In this sense, the corresponding relationship is that of a monochromatic beam of light—that with a single frequency and single wavelength—with that of a beam of electrons of fixed energy. [Pg.72]

IR drop is zero. Excellent for nonaqueous solution work Intellectually attractive because it mirrors a chemical reaction with fixed energy of activation tor each potential... [Pg.701]

Around a fixed energy E, the average reaction rate is given by the famous RRKM formula, which can be derived from both quasiclassical and quantal considerations [71, 72]. In the context of the Wigner matrix theory [133], the rate is given by the sum of the half-widths of all the open channels. The rate is thus the product of the number v(E) of open channels and the rate per channel fcchannei(E) = l/hnav(E), where h is the Planck constant. The average reaction rate is obtained as [134, 135]... [Pg.539]


See other pages where Fixed energy is mentioned: [Pg.18]    [Pg.121]    [Pg.1027]    [Pg.1450]    [Pg.164]    [Pg.381]    [Pg.804]    [Pg.272]    [Pg.122]    [Pg.28]    [Pg.31]    [Pg.79]    [Pg.97]    [Pg.99]    [Pg.240]    [Pg.428]    [Pg.21]    [Pg.108]    [Pg.266]    [Pg.57]    [Pg.419]    [Pg.408]    [Pg.125]    [Pg.230]    [Pg.433]    [Pg.20]    [Pg.275]    [Pg.225]    [Pg.298]    [Pg.298]    [Pg.156]    [Pg.536]    [Pg.25]    [Pg.533]    [Pg.24]   
See also in sourсe #XX -- [ Pg.32 ]




SEARCH



© 2024 chempedia.info