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Integral First

Equations 4.54 and 4.55 can be integrated. Using Equation 4.54 in Equation 4.55 gives [Pg.293]

This is the general relation of local c and fj to the boundary values i, Ci, and Jo- As before, the subscript 1 marks the values at the CL/GDL interface. [Pg.293]

By setting in Equation 4.63 x = 0, a useful general relation is acquired for the overpotential drop in the CL  [Pg.293]

Care should be taken when using this relation in the case of ideal feed transport. In this case, b oo, while co Ci, and the product b(ci - co) remains finite. In the section Another Explicit Form of the Polarization Curve it is shown that at small cell currents, lim b ci — Co) =jo/2. With this. Equation 4.64 transforms to [Pg.294]

at small currents, the overpotential drop increases linearly with the cell current density. [Pg.294]


It is manifestly impossible to measure heat capacities down to exactly 0 K, so some kind of extrapolation is necessary. Unless were to approach zero as T approaches zero, the limiting value of C T would not be finite and the first integral in equation (A2.1.71) would be infinite. Experiments suggested that C might... [Pg.369]

The first integral on the right-hand side is zero it becomes a surface integral over the boundary where (W - ) = 0. Using the result in the previous equation, one obtains... [Pg.391]

Since there is no conical intersection in the buffer zone, CTq, the second integral is zero and can be deleted so that we are left with the first and the third integrals. In general, the calculation of each integral is independent of the other however, the two calculations have to yield the same result, and therefore they have to be interdependent to some extent. Thus we do each calculation separately but for different (yet unknown) boundary conditions The first integral will be done for Gi2 as a boundary condition and the second for G23. Thus A will be calculated twice ... [Pg.670]

This latter modified midpoint method does work well, however, for the long time integration of Hamiltonian systems which are not highly oscillatory. Note that conservation of any other first integral can be enforced in a similar manner. To our knowledge, this method has not been considered in the literature before in the context of Hamiltonian systems, although it is standard among methods for incompressible Navier-Stokes (where its time-reversibility is not an issue, however). [Pg.285]

The first integral ean be evaluated using integral equation (18) with a = L... [Pg.146]

The first integral is zero (see the evaluation of this integral for E i above in part a.) The... [Pg.148]

Taking into account the conditions (5.187), we first integrate by parts in the left-hand side of the inequality obtained and next we integrate in t. Simultaneously, the integration by parts in t is fulfilled. This gives the inequality... [Pg.333]

The first integral on the right-hand side is the rate of work done on the fluid in the control volume by forces at the boundaiy. It includes both work done by moving solid boundaries and work done at flow entrances and exits. The work done by moving solid boundaries also includes that by such surfaces as pump impellers this work is called shaft work its rate is Ws-... [Pg.633]

Ayu is the chemical potential difference between the regions behind and before the step edge, S is the integration path along the step. The first integral must be transcribed such that it contains 6 S) as a product in... [Pg.875]

The first integral of this expression goes to zero because / vanishes strongly at % = + oo the second yields ... [Pg.30]

In the partial case when a is constant the first integral on the right-hand side of Eq. (8.66) may be expressed as... [Pg.363]

From the time when it was shovm that micro flow reactors can provide valuable contributions to organic chemistry, it was obvious to develop them further and their workflow towards modern screening techniques [20]. It was especially the finding of high reaction rates, the capability to transport and transform minute sample volumes and the first integration of analytics that paved the way to a parallelization of micro flow processing. These benefits were combined with the ease of automation of a micro flow system. By this means, the potential of on-line analysis of the reactions can be fully exploited. [Pg.523]

Both integrals on the right hand side can be easily expressed in terms of elementary functions. First, integration by parts gives... [Pg.125]

It is important to note that expression (23) can be applied to the crystalline phase intensities only if we include, in the first integral, its own smooth diffuse background and not just the intensity belonging to the crystalline peaks. In fact, a pure crystalline sample also has a smooth background due to the incoherent inelastic scattering (i.e. Compton scattering), the TDS, disorder scattering and, very often, unresolved tails of overlapped peaks. [Pg.137]

Since the first integral on the right-hand side vanishes according to equation (6.37) and the second integral equals unity according to (6.25), the result is... [Pg.165]

According to equation (6.39), the first integral vanishes and the second integral equals (2X), giving the result... [Pg.166]

A. Jorba, A methodology for the numerical computation of normal forms, centre manifolds and first integrals of Hamiltonian systems, Exp. Math. 8, 155 (1999). [Pg.238]

The first integral denotes the rest period, — oo < t < 0, where the strain rate is zero. The second integral contains a relaxation function which we chose very broad, including relaxation times much larger than the period In/iD. Integration and quantitative analysis clearly showed (without presenting the detailed figures here) that the effect of the start-up from rest is already very small after one cycle... [Pg.209]

In order to demonstrate completeness of a SAXS fiber pattern in the 3D reciprocal space, it is visualized in Fig. 8.16. The sketch shows a recorded 2D SAXS fiber pattern and how it, in fact, fills the reciprocal space by rotation about the fiber axis. V3. Let us demonstrate the projection of Eq. (8.56) in the sketch. It is equivalent to, first, integrating horizontal planes in Fig. 8.16 and, second, plotting the computed number at the point where each plane intersects the S3-axis. [Pg.151]

It is now necessary to evaluate the integrals in Eq. (10C) using the UCpert operator. Terms to first order in Sz will be retained. For the first integral,... [Pg.334]


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