Fill balance geometrical

Designing an imager for automotive applications necessitates balancing various factors. A high geometrical resolution (e.g., 4kx4k) can only be achieved by squeezing pixel pitch and in sequence the fill factor and sensitivity. The need for deep submicron CMOS processes shifts the maximum of the spectral response towards the blue end of the visual spectrum with small quantum efficiency. 

The initial approach angle (C-H-M) of about 130° was rationalized in terms of a proposed interaction between the C - H o bond and an empty metal d orbital, and back-donation from a filled d orbital to a a orbital of the C-H system, but this angle may also result from geometrical factors. The role of steric and conformational effects in the balance between cyclometallation and attack on an external substrate (such as an alkane), was discussed in the context of the above reaction path. The conclusion was that sterically uncongested metal systems are more likely to activate alkanes, than to undergo cyclometallation. 

Mold Filling Imbalances in Geometrically Balanced Runner Systems ANTEC 98. John P. Beaumont, Jack H. Young, Matthew J. Jaworski... 

Mold Filling Imbalances in Geometrically Balanced Runner Systems ANTEC 03... 

Since this reverse comer effect imbalance still deals with shear, it is important to understand the sensitivity of the filling imbalance to injection flow rate along with the sensitivity of different materials to these mold filling imbalances in a geometrically balanced runner. 

Beaumont J.P., Young J.H. Jaworski M.J. Mold Filling Imbalances in Geometrically Balanced Runner Systems, ANTEC, pp 599-604, 1998. 

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