Figure captions

The slopes of the fimctions shown provide the reaction rates according to the various definitions under the reaction conditions specified in the figure caption. These slopes are similar, but not identical (nor exactly proportional), in this simple case. In more complex cases, such as oscillatory reactions (chapter A3.14 and chapter C3.6). the simple definition of an overall rate law tluough equation (A3.4.6) loses its usefiilness, whereas equation (A3.4.1) could still be used for an isolated system. 

The main phenomenological difference in BM compared to MG is a broadening of the resonance peak at which, however, does not shift. The model calculations in Fig. 11 have been performed for spheres (N = 1/3) with filling factors of 0.5 and 0.9. The parameters, chosen to be equal for both models, are given in the figure caption. It immediately appears that we will not find any drastic difference in the interpretation of the data for the MG or the BM model. 

Continuing the process of updating static art to new balloon-caption art in which explanations previously presented in the text narrative or figure captions move into the art itself. We felt that todays students are more likely to see and understand it with such placement. 

The Chin-Gilman parameters (H/G) are given in the figure captions. Note that the value for the bcc metals (0.02) is about five times greater than the value for the fee metals (0.0044). Thus the bcc metals deformation harden much more rapidly than the fee metals. 

A set of SER spectra for adsorbed azide on silver, obtained for the same surface and solution conditions and for a similar sequence of electrode potentials as for the PDIR spectra in Figure 1, is shown in Figure 2. (See the figure caption and reference 7 for experimental details.) Inspection of these SER spectra in comparison with the PDIR results illustrate some characteristic differences in the information provided by the two techniques. Most prominently, in addition to the Nj" j/as band around 2060 cm"1, the former spectra exhibit three other features at lower frequencies attributable to adsorbed azide vibrations. By analogy with bulk-phase spectra for free and coordinated azide (15), the 1330 cm"1 SERS band is attributed to the N-N-N symmetric stretch, vt (2). The observation of both i/a and j/aa features in the SER spectra differs from the surface infrared results in that only the v band is obtained in the latter (2). The appearance of the vn band in SERS is of interest since this feature is symmetry forbidden in the solution azide Raman spectrum. 

Actual operating conditions can be found in the figure caption. A given limitation of SFC, relative to HPLC, as described is the ability to dissolve samples in a solvent system compatible with the methanol/ carbon dioxide mobile phase. For this particular mobile phase, other compatible sample diluents that worked effectively are pure methanol,... 

The findings are summarized below, and in Figures 6, 7 and 8. Complete references are provided in the text and in the figure captions. Implications of these data for understanding Mo geochemical cycling, and for application of this understanding to paleoredox questions, are discussed in the subsequent section. 

Figure 6.6 shows Am versus the number of effective phonons, p, for the same three materials of Figure 6.5. The energy of the effective phonons for each host crystal is indicated in the figure caption. An exponential decrease in the nonradiative rate with...

All the samples were prepared by mixing of concentrated solutions of the interacting components and were allowed to rest for 24 hours. Measurements were then performed at 30 C. For each series of experiments the PAA concentration was kept constant, and the polybase concentration varied in order to adjust the ratio r = [polybase]/[PAA] to the required value. The concentration of PAA is 0.02 or 0.1 unit mol/1 as given in the figure captions. The polybase concentration is obtained from [PAA] and r values [polybase] = r.[PAA]. 

Exceptions include (1) titles, (2) section headings, (3) figure captions, and (4) table titles. 

Graphics in proposals are sometimes "boxed". In some cases, the text is wrapped around the graphic. To save space, slightly smaller font is sometimes allowed for figure captions. 

Table titles and figure captions are reproduced as written hence, different formatting conventions are observed (e.g., some table titles are centered, bolded, and in title case others are left-justified, unbolded, and in sentence case). 

Almost all spectra were acquired on a AMX-600 Bruker NMR spectrometer equipped with a 5 mm inverse broad-band probe. The only exception were the gradient-enhanced spectra acquired on an INOVA-600 Varian NMR spectrometer using a 5 mm triple-resonance probe with z gradients. The experimental details are given for each spectrum in the figure captions. 

Solution The calculated concentration profiles at f= 100 years are plotted in Figure 4-32. The calculation of the interface concentrations is explained in the figure caption. Because diffusion in olivine is much more rapid, the profile is longer in olivine and deviation from the initial concentration is smaller. 

The methane oxidation studies used a schematic similar to the above except that the reactor section was fabricated entirely from quartz and reaction temperatures fi-om 600 to 1000°C were examined. The precise conditions for the experiments discussed are indicated in the figure captions. 

In the laboratory experiments, DOC monolith samples (length 7.5 cm, diameter 1.4 cm) with rather thin catalyst layer coating ( 25 pm) were employed to minimize the internal diffusion effects. The samples were placed into a thermostat to suppress the formation of temperature-gradients along the channels. In the course of each experiment, the temperature of the inlet gas and the monolith sample was increased at a constant rate of /min within the range of 300-800 K. The exhaust gases at the inlet of the converter were simulated by synthetic gas mixtures with defined compositions and flow rates (cf. individual figure captions all gas mixtures contained 6% C02 and 6% H20). 

To estimate the effect of the methanol on Kid, assume that a is about 1 in Eq. 9-34. Get the of value of phenanthrene from the PAH data summarized in Fig. 5.8 using (see figure caption) ... 

In order to estimate how the bioavailability of benzo(a)pyrene (BP) is affected by DOM, you want to assess the speciation of this compound as a function of DOM quantity and quality. To this end, calculate the fw value of BP for aqueous solutions (pH 7, 25°C) containing (a) 10 mg DOC-L"1 and 100 mg DOC-L"1, respectively, and (b) assuming DOM qualities as reflected by the LFERs 1 and 7 in Fig. 9.16 (see figure caption for slopes and intercepts). Note that DOM 1 represents a humic acid that exhibits a high affinity for PAHs, whereas DOM 7 is a fulvic acid with a low affinity. Hence, the two DOMs may represent extreme cases with respect to sorption of apolar and weakly polar compounds in natural waters. 

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