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Experimental design defined

As the vertices of a simplex are not linearly related to each other, an experimental design defined by a simplex forces the experimenter to change each variable in relation to each other in an uncorrelated manner over the set of k + 1) experiments. A consequence of this is that the experimental result will carry... [Pg.226]

Bob is particularly concerned that, although analytical chemistry forms a major part of the UK chemical industry s efforts, it is still not considered by many to be a subject worthy of special consideration. Consequently, experimental design is often not employed when it should be and safeguards to ensure accuracy and precision of analytical measurements are often lacking. He would argue that although the terms accuracy and precision can be defined by rote, their meanings, when applied to analytical measurements, are not appreciated by many members of the scientific community. [Pg.18]

A two levels of full factorial experimental design with three independent variables were generated with one center point, which was repeated[3]. In this design, F/P molar ratio, Oh/P wt%, and reaction temperature were defined as independent variables, all receiving two values, a high and a low value. A cube like model was formed, with eight comers. One center point (repeated twice) was added to improve accuracy of the design. Every analysis results were treated as a dependent result in the statistical study. [Pg.869]

ENA was recently used for remote on-line corrosion monitoring of carbon steel electrodes in a test loop of a surge water tank at a gas storage field. An experimental design and system for remote ENA and collection of electrochemical impedance spectroscopy (EIS) data (Fig. 13) have been presented elsewhere. In the gas storage field, noise measurements were compared with electrode weight loss measurements. Noise resistance (R ) was defined as... [Pg.230]

Second is the application of a wide range of experimental designs and techniques. DNA CT is observed in a diverse array of systems over different distance and time regimes. Consequently, a versatile approach which draws upon complementary methods is required to explore different facets of this chemistry and develop a complete picture. We interrogate a variety of nucleic acid assemblies using spectroscopic, biochemical and electrochemical tools to define mechanistic features, exploit biological applications, and explore biological consequences of DNA CT. [Pg.81]

The problem of multianalyte analysis is of high importance in different methods of analytical chemistry. The measurements with sensor arrays are not an exception they are always complicated by multicomponent calibrations, as the number of these calibrations, even if defined in accordance with the modem principles of experimental design, increases exponentially with the increase in the number of analytes. [Pg.131]

ANOVA (analysis of variance), commercial experimental design software compared, 8 398t Anoxic conditions, defined, 3 757t ansa-metallocenes, 16 90, 94 ansa-zirconocene catalysts,... [Pg.60]

The goal of the four principles of experimental design is statistical efficiency and the economizing of resources.The single most important initial step in achieving such an outcome is to clearly define the objective of the study get a clear statement of what questions are being asked. [Pg.880]

In the following discussion, we shall again separate the terms of a hyperbolic model and identify two parameters Cl and C2. As before, each of these two parameters will be a collection of terms, one of which is multiplied by conversion and one not multiplied by conversion. In previous formulations, however, we have oriented the discussion toward a familiar type of experimental design in kinetics conversion versus space-time data at several pressure levels. Consequently, the parameters Cx and C2 were defined to exploit this data feature. Another type of design that is becoming more common is a factorial design in the feed-component partial pressures. [Pg.147]

After selection of the experimental design, the experiments can be defined. For this purpose, the level symbols, —1 and +1, as given in Tables 6 and 7, are replaced by the real factor values, as for instance shown in Tables 2 and 3, respectively, yielding the factor level combinations to be performed. Dummy factors in PB designs can be neglected during the execution of the experimental work. [Pg.199]

As an alternative, SST limits can be determined from the results of a robustness as recommended by the ICH. It can be done using the worst-case results for the response, derived from the experimental design results. This allows defining SST limits for responses such as resolution or peak asymmetry. The main idea behind the approach is that the most extreme results are considered, obtained under experimental conditions resulting in acceptable quantitative determinations. SST limits can thus only be meaningfully derived when the tested method is considered robust concerning its quantitative aspect. Then, nowhere in the domain, described by the experimental design, a problematic quantitation occurs, even not at the conditions where the SST responses are worst. [Pg.208]

As already mentioned, an experimental design approach is preferred to evaluate method robusmess. It is a multivariate approach, evaluating the factor effects on the responses by varying the factors simultaneously, according to the experimental conditions defined by the design. [Pg.212]

Study means an experiment or set of experiments in which a test item is examined. The study plan defines the objectives and experimental design of the study. [Pg.100]


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