5-Ethylthio-2-phenyl

Ethylthio-phenyl-trifluor-phosphoran88 Ein Gemisch aus 9,2 g (50 mmol) Phenyl-tetrafluor-phosphoran und 6,7 g (50 mmol) Ethylthio-trimethyl-silan werden 4Stdn. auf 80° crhitzt. Der Kolbenriickstand wird i.Vak. de-stillicrt Ausbeute 7,8 g (69%) Sdp. 59-6070,01 Torr (1,33 Pa). 

Hydroxylamin N-tert.-Butyl-N-(4-ethylthio-phenyl)- E16a, 145 (Ar-NO + R-M)... 

Formation of 2-ethylthio-phenyl isocyanide and 2-(methylthio)benzothiazole. 

Zur Herstellung von l-(2-Ethylthio-4-phenyl-l,3-thiazol-2-yl)-4-phenyl-imidazol aus 4(5)-Phe-nyl-imidazol mit 2-Ethylthio-4-phenyl-l,3-dithiolium-perchlorat s. Bd. E4, S.713. 

Br —CH2 —CO —CgH5 H5Cj-OH Ruckfl. 3-Amino-1-methyl-2- (2-oxo-2-phenyl-ethylthio J -benzimidazolium-bromid 85 120-125 366... 

Durch thermische Umlagerung von 3-(Ethylthio-carbonyl)-2-oxo-5-phenyl-2,3-dihydro-l,3,4-oxadiazol laBt sich 2-Ethylthio-5-phenyl-1,3,4-oxadiazol (45% Schmp. 39-40°) neben 5-Phenyl-2-thiono-2,3-dihydro- und 3-Ethyl-5-phenyl-2-thiono-2,3-dihydro-1,3,4-oxadiazol iso-lieren550. 

Thiazolidine-2-thione, 3-allyl-, 56, 79 2-Thiazohne, 2-allylthio-, 56, 77 2-Thiazoline, 2-benzylthio-, 56, 82 2-Thiazoline, 2-cmnamylthio-, 56, 82 2 Thiazoline, 2 ethylthio, 56, 82 2-Thiazohne 2-mercapto-, 56, 77 2-Thiazoline, 2-methylthio-, 56, 82 2-Thiazohne, 2-(4-phenyl-l-buten-3-yl)-thio-, 56, 78... 

Interaction with diethyl sulfide occurs with simultaneous elimination of nitrogen and formation of a sulfonium salt of type 306 its hydrolytic decomposition yields 5-hydroxy- (307) and 5-ethylthio-3-phenyl-l,2,4-thiadiazole (308), in proportions dependent upon the hydrogen ion concentration of the medium.160... 

Disubstituted furans (130) can be obtained by treatment of j8-alkoxy- and j8-arylthio-a,j8-unsaturated ketones, for example 3-methoxy-l-phenyI-2-buten-l-one (128) or 3-ethylthio-l-phenyl-2-buten-l-one (129), with dimethylsulfonium methylide (79JHC815, 69TL679). The possible reaction pathway (Scheme 27) shows the initially formed epoxides as rearranging by ring opening at the tertiary epoxide carbon atom. 

Methane Dichloro-fluoro-(l-methyl-2-oxo-2-phenyl-ethylthio)-ElOb,. 189 (Educt)... 

Dimethyl- -(1-ethylthio-ethylester) E2, 271 Dimethyl- -[(4-fluor-phenyl)-methylester] E2, 272 Dimethyl- [2-(4-methylthio-phenylthio)-ethylester] aus Dimethyl-dithiophosphinsaure und 2-Brom-l-(4-methylthio-phenylthio)-ethan XII/1, 283 Dimethyl- -[(4-methylthio-phenylthio)-methyl-ester] XII/1, 283 Dimethyl- -phenylester E2, 269 Dimethyl- -trimethylsilylester E2, 266 Dimethyl- -(2-vinylthio-ethylester) E2, 271 Diphenyl- XII/1, 59, 227, 279, 284. 289 El, 172-El, 262, 265, 269, 271ff., 274 aus Benzol, Phosphor(V)-sulfid und Aluminium-chlorid XII/1, 272... 

Methyl-propyl- -(2-ethylthio-ethylester) E2, 272 Methyl-propyl- -[(methoxycarbonyl-methylthio)-methylester] E2, 272 Methyl-2-thienyl- E2, 262 Phenyl-propyl- E2, 262 -Thiobenzoesaure-Anhydrid XII/1, 288... 

Benzyl-diethoxy- E2, 134 Benzyl-diisopropyloxy- E2, 134 Benzyl-ethyl-phenyl- -tosylimid E2, 113 Benzyl-methyl-phenyl- -tosylimid E2, 113 Benzyloxy-diphenyl- E2, 17, 18 Benzyloxy-ethoxy-hydroxy- E2, 187 Bis-[2-biphenylyl]- E2, 876 [2,6-bis-(2-tetrahydropyranyloxy-methyl)-phenyl]-Bis-[4-brom-anilino]-phenyl- E2, 416 Bis-[2-brom-ethoxy]-(2-brom-ethyl)- E2, 196 Bis-[butylthio]-ethyi- E2, 79, 408 Bis-[2-chlor-cthoxy]-butyl- E2, 196 Bis-[2-chlor-ethoxy]-(2-chlor-ethyl)- E2, 196 Bis-[2-chlor-ethoxy]-methyl- E2, 196 Bis- 2-chlor-ethoxy]-phenyl- E2, 196, 197, 202 Bis- 2-ehlor-ethoxy]-(2-phcnyl-vinyl)- E2, 196 Bis-(2-ehlor-ethoxy]-vinyl- E2, 196 Bis-j 2-chlor-ethyl]-methyl- E2, 205 Bis-[chlormethyl]-dodecyl- E2, 22 Bis-12-cyan-ethyl]- E2, 223 Bis- diethylamino]-butyl- E2, 486 Bis-[ l-cthinyl-butyl]-phenyl- E2, 197 Bis-[ethoxycarbonyl-methyl]-chlor- E2, 251 Bis-[ethylthio]-ethyl- E2, 408 Bis-[4-methoxy-aniliiio]-phenyl- E2, 416 Bis-[4-methyl-phenylJ-phenyl- K2, 105 Bis- 4-methyl-phcnyl]-phenyl- -phenylsulfonvlimid E2, 105... 

Dipipcridino-phenyl- E2, 482 Di-2-propinyloxy-ethyl- E2, 196 Dipropyl-(4-methoxy-N-lfaethyl-amlino)- E2, 296 Dipropyl-propyloxy- E2, 212 Divinyl-phenyl- E2 874 Ethoxy-ethyl-methoxycarbonylmethyl- E2, 21 Ethoxy-ethyl-phenyl- E2, 23 Ethoxy-hydroxy-methyl- E2, 130, 131 Ethoxy-hydroxy-phenyl- E2, 131, 185, 187, 190, 422 Ethoxy-(2-propinyloxy)-trifluormethyl- E2, 196 Ethyl-ethylthio-(l-methyl-3-oxo-butyl)- E2, 223 Ethyl-methyl-phenyl- -tosylimid E2, 11.3 Ethyl-pbenyl-propyloxy- E2, 281 F.thyl-phenyl-propylthio- E2, 225. Hydroxy-(2-isopropyl-5-methvl-cyclohexvloxv)-methyl- E2, 392... 

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