Ethyl-»-amylamine

Caprolactam is a thermally unstable compound which on distillation may form methyl-, ethyl-, propyl-, and n-amylamines. Also, at high temperatures, CL reacts widi oxygen to form hydroperoxides which in the presence of iron or cobalt ions are converted into adipimide. /V-alkoxy compounds are also formed by the reaction of CL with aldehydes during storage. 

Ethyl-3-methylpyridine (also known as aldehyde-collidine ) has been prepared by heating aldehyde-ammonia aldehyde-ammonia and acetaldehyde or paraldehyde aldol-ammonia and ammonia paraldehyde and ammonia <> 11,12 acetamide,1 or acetamide and phosphorus pentoxide ethylene glycol and ammonium chloride ethylidene chloride or bromide and ammonia ethylidene chloride and acetamide, ethylamine, or n-amylamine crotonic acid and a calcium chloride-ammonia complex 1 and by passage of acetylene or acetaldehyde and ammonia over alumina and other catalysts. 

The relative reaction rates of several amines with phenyl isocyanate in ether at 0°C have been determined. Aniline is about half as reactive as ethyl-, n-propyl-, n-butylamine, and n-amylamine is between eight and ten times as reactive as ammonia [28]. 

Sample preparation and derivatization methods for GC analysis of BAs have been also proposed. In a method developed by Daudt and Ough (1980), amines are distilled from the alkalized grape juice or wine sample and trapped in an acidified solution. After concentration under vacuum, methylamine, dimethylamine, ethylamine, diethylamine, n-propylamine, isobutylamine, a-amylamine, isoamylamine, pyrrolidine, and 2-phenethylamine in their salt form are derivatized with triflu-oroacetic (TFA) anhydride. TFA derivatives are extracted with ethyl ether and analyzed by GC-MS with a capillary fused silica poly( ethylene) glycol (PEG) column and the following oven temperature program 8 min at 70 °C, l°C/min to 160 °C, isotherm for 90 min. 

Ammonium acetate Aniline Benzanthrone Bromine Carmine (Coccus cacti) Carminic acid 2-Chlorophenol Crystal violet lactone Diaminodiphenic acid Di-n-amylamine Diazoaminobenzene o,a-Dichlorotoluene Dimethoxypropane 4-Dimethylaminoazobenzene-4-sulfonic acid, sodium salt p-Dimethylaminobenzaldehyde 4-Dimethylaminobenzene 6-Dimethylaminophenylazobenzothiazole N,N-Dimethylaniline Dinitrotoluene 2,4-Dinitrotoluene Direct blue 8 Direct blue 10 Direct blue 25 Direct blue 218 Direct orange 6 Direct violet 32 Disperse blue 7 Disperse red 60 Dodecene-1 N-(p-Ethoxycarbonylphenyl)-N -ethyl-N -phenylformamidine Ethylene cyanohydrin Ethylene thiourea... 

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