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Ethanol DEMS study

Wang Q, Sun GQ, Jiang LH, Xin Q, Sun SG, Jiang YX, Chen SP, Jusys Z, Behm RJ (2007) Adsorption and oxidatimi of ethanol on colloid-based Pl/C, PtRn/C and Pt3Sn/C catalysts in situ FTIR spectroscopy and on-line DEMS studies. Phys Chem Chem Phys 9 2686-2696... [Pg.24]

Garcia G, TsiouvarasN, Pastor E, PenaMA, Fierro JLG, Martmez-Huerta MV (2012) Ethanol oxidatitm on PtRuMo/C catalysts in situ F ilR spectroscopy and DEMS studies. Int J Hydrogen Energy 37(8) 7131-7140... [Pg.1616]

Wang H, Jusys Z, Behm RJ (2006) Ethanol electrooxidation on carbon-supported Pt, PtRu and Pt3Sn catalysts a quantitative DEMS study. J Power Sources 154(2) 351-359... [Pg.1616]

S. Sim, M.C. Halseid, M. Heinen, Z. Jusys, R.J. Behm, Ethanol electrooxidation on a carbon-supported Pt catalyst at elevated temperature and pressure a high-temperature/high-pressure DEMS study, J. Power Sources 190 (2009) 2-13. [Pg.64]

Abstract In this chapter, we present new insights in direct alcohol fuel cell-related anode electrocatalysis based on quantitative differential electrochemical mass spectrometry (DEMS) studies. First, we review the history and development of the DEMS technique, as well as the calibration method for quantification. We then discuss some contributions of quantitative DEMS to the study of the mechanism of methanol electrooxidation on Pt and PtRu model catalysts. We also discuss quantitative DEMS studies of the mechanism of dissociative adsorption and electrooxidation of ethanol and acetaldehyde at Pt, Pt3Sn, PtRu, and PtRh nanoparticle catalysts. Finally, the mechanism of dissociative adsorption and electrooxidation of ethylene glycol and its oxidative derivatives on carbon-supported Pt, Pt3Sn, and PtRu nanoparticle catalysts are discussed, based on quantitative DEMS results. [Pg.33]

Schmiemann U, Muller U, Baltruschat H. 1995. The influence of the surface-structure on the adsorption of ethene, ethanol and cyclohexene as studied by DEMS. Electrochim Acta 40 99-107. [Pg.205]

A quantitative study of the electro-oxidation of ethanol on carbon-supported Pt, PtRu and PtsSn catalysts was made by Behm and co-woikers " nsing combined voltarmnetric and on-line Differential Electrochemical Mass Spectrometry measnrements (DEMS). [Pg.460]

Itmumerable mechanistic studies of alcohol oxidation on Pt-based electrocatalysts in acidic media have been published over the last few years. Methanol, " ethanol ° and ethylene glycol have been the most studied substrates and their oxidation paths on Pt or Pt alloys have been substantiated using a variety of in situ, extra situ and operando techniques as well as quantum mechanical calculations. The experimental techniques include reflection IR spectroscopy (IR), surface enhanced IR asbsorption spectroscopy (SEIRAS), " attemrated total reflection-IR absorption spectroscopy (ATR-IRAS), differential electrochemical mass spectroscopy (DEMS), single potential alteration IR spectroscopy... [Pg.245]

The identification of the ethanol oxidation products and their quantification has been also carried out by means of DEMS. Behm and coworkers have studied thoroughly the distribution of products resulting of the electrooxidation of ethanol in acid medium at different temperatures and ethanol concentrations with carbon supported platinum-based catalysts... [Pg.41]

F.C. (2002) Electro-oxidation of ethanol on Pt, Rh, and PtRh electrodes a study using DEMS and in-situ FTIR techniques. [Pg.125]

See other pages where Ethanol DEMS study is mentioned: [Pg.460]    [Pg.41]    [Pg.64]    [Pg.100]    [Pg.383]    [Pg.180]    [Pg.383]    [Pg.430]    [Pg.408]    [Pg.888]    [Pg.39]   
See also in sourсe #XX -- [ Pg.43 ]



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