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Esters organopalladium derivatives

B.iii. Organopalladium Derivatives Generated from Allyl Esters and Ethers... [Pg.561]

E. REACTIONS WITH ORGANOPALLADIUM DERIVATIVES GENERATED FROM ALLYL AMIDES AND ESTERS... [Pg.596]

One of the most synthetically useful reactions involving organopalladium intermediates is that between rr-allyl complexes and relatively stable carbanions such as those derived from malonate esters and jS-ketoesters. The tt- allyl complexes can be synthesized separately and used in stoichiometric amount or they can be generated in situ by reaction of allylic acetates with a catalytic amount of tetrakis (triphenylphosphine)palladium. In the catalytic version of the reaction, the tt-allyl complex is formed by reaction of the allylic acetate and the Pd(0) species which is regenerated in the elimination step. [Pg.287]

See other pages where Esters organopalladium derivatives is mentioned: [Pg.196]    [Pg.25]    [Pg.550]    [Pg.19]    [Pg.1336]    [Pg.217]    [Pg.842]    [Pg.217]    [Pg.3548]    [Pg.966]    [Pg.3547]    [Pg.583]    [Pg.772]   


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Organopalladium

Organopalladium derivatives

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