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Enzyme-Catalyzed Nucleophilic Substitutions of Alkyl Halides

Enzyme-Catalyzed Nucleophilic Substitutions of Alkyl Halides [Pg.335]

This haloalkane dehalogenase is believed to act by using one of its side-chain carboxylates to displace chloride by an Sn2 mechanism. (Recall the reaction of carboxylate ions with alkyl halides from Table 8.1.) [Pg.335]

The product of nucleophilic substitution then reacts with water, restoring the enzyme to its original state and giving the observed products of the reaction. [Pg.335]

This stage of the reaction proceeds by a mechanism that will be discussed in Chapter 19. Both stages are faster than the reaction of 1,2-dichloroethane with water in the absence of the enzyme. [Pg.335]

Enzyme-catalyzed hydrolysis of racemic 2-chloropropanoic acid is a key step in the large-scale preparation (2000 tons per year ) of (S)-2-chloropropanoic acid used for the preparation of agricultural chemicals. [Pg.335]


Enzyme-Catalyzed Nucleophilic Substitutions of Alkyl Halides 335... [Pg.322]

AN ENZYME-CATALYZED NUCLEOPHILIC SUBSTITUTION OF AN ALKYL HALIDE... [Pg.339]

An Enzyme-Catalyzed Nucleophilic Substitution of an Alkyl Halide... [Pg.1329]

A new boxed essay, An Enzyme-Catalyzed Nucleophilic Substitution of an Alkyl Halide, in Chapter 8 makes a direct and simple connection between S>j2 reactions and biochemistry. [Pg.1265]


See other pages where Enzyme-Catalyzed Nucleophilic Substitutions of Alkyl Halides is mentioned: [Pg.543]   


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2-Substituted alkyl 3-

Alkyl halides substitution

Alkyl halides, nucleophilic substitution

Alkyl substitute

Alkyl-enzyme

Alkylation nucleophilic

Alkylation of nucleophiles

Enzyme-catalyzed

Enzymes alkyl halides

Enzymes catalyze

Enzymes substitution

Enzymic substitution

Halide nucleophilicities

Halides nucleophilicity

Nucleophile alkyl

Nucleophile-catalyzed

Nucleophiles alkylations

Nucleophiles, alkylation

Nucleophilic alkyl substitution

Nucleophilic alkyl substitution enzyme catalyzed

Of alkyl halides

Substituted halides

Substitution alkylation

Substitution halides

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