Enthalpy-entropy compensation viewed from

MOLECULAR RECOGNITION IN CHEMISTRY AND BIOLOGY AS VIEWED FROM ENTHALPY-ENTROPY COMPENSATION EFFECT ... 

Inoue, Y. Wada, T. Molecular Recognition in Chemistry and Biology as Viewed from Enthalpy-Entropy Compensation Effect. In Advances in Supramolecular Chemistry Gokel. G.W.. Ed. JAI Press Greenwich, CT, 1997 Vol. 4. 55-96. 

Y. Inoue and T. Wada, Molecular recognition in chemistry and biology as viewed from enthalpy-entropy compensation effect, in Advances in Supramolecular Chemistry,... 

All known LC systems under critical and limiting conditions reported over the last 25 years have been summarized. This collection, of over 180 systems, indicates for approximately 37 homopolymers, the most appropriate systems from the point of view separation up to high molar mass and with full recovery. It also enables to reduce the time which would be necessary for identifying the composition of the mobile phase. Suitable alternatives for the separation of different parts of a studied copolymers under conditions of entropy-enthalpy compensation can be identified. Furthermore, the data have been tested from point of view of correlation s between some experimental characteristics of the critical systems. 

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