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Energy of localization

In the case considered, by referring to Fig, 3, we see that the peak energy (0.45 eV) conforming to a solvated electron is much less not only than the photoionization energy, but even the difference in the equilibrium energies of localized and delocalized states. Hence, here only transition to the bound excited state can take place . The same, though with less confidence (because of lesser reliability of the numerical values used), can be said also about the peak conforming to Na"-type associates. ... [Pg.166]

Localization Function /(02) versus Adsorption Energy of Localizing Group k and Sample Type (adsorption on alumina) ... [Pg.350]

If, however, ET from the oxide layer is not influence by the imderlying Fe , the driving force will be determined by Ecb of the oxide, EpCoxide), or the energies of localized states or impurity bands. For the reduction of CCI4 by passivated iron,... [Pg.311]

G (z) Green function of local f-electrons in state a for a fictitious ( effective ) impurity, designed to mimic f-electrons in a lattice-periodic system self energy of f-electrons in state k, a for a lattice-periodic system 2 (z) self energy of local f-electrons in state a for a fictitious ( effective ) impurity designed to f-electrons in a lattice-periodic system... [Pg.345]

Sum] Inelastic scattering of slow neutrons in Fe-Ni austenite Energy of local oscillation of C atoms measured at 75.8 meV... [Pg.288]

A = half width in energy of localized state S = crystal field splitting e(n) = fraction of time 4f shell has configuration 4f ... [Pg.798]

The pressure effect on the energetic stmcture of Ca W04 Pr and CaW04 Tb is presented in Fig. 4.32a, b, respectively. The energy of localized states of Pr and Tb " increases with respect to the band states and the ITE state. In Fig. 4.32, the pressures Pi and P2 are the pressures at which the emission from the upper m and lower "Z emitting states is quenched. In the paper [202], values of Pi and P2 have been estimated for CaW04 Pr and CaW04 Tb. The respective data are listed in Table 4.9. The values of Pi and P2 allow calculating of the pressure-induced shift... [Pg.131]

The reaction field is absent if the excited state is noncharged. The energy of locally excited states does not depend on polarization forces. The electronic polarization from the molecules themselves is accounted for in the quantum chemical calculation. It is important to include a few solvent molecules to fill the sphere with radii a and a, around D and A, respectively, with solvent molecules. [Pg.349]

We stressed in section 1 that the one-electron approximation is fundamentally incapable of accurately predicting the excitation energies of localized states, and in... [Pg.338]

The energy of localization of such a fractal state in an additional potential fluctuation of size L was obtained from the Thouless scaling argumentand showed that the original H-L result was regained for d < 2, On the other hand, we found that for d > 2, Eq. (5) was to be replaced by... [Pg.23]


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See also in sourсe #XX -- [ Pg.139 ]




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Average Local Ionization Energies of Molecules

Behavior of Deposited Energy with Respect to Localization

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Energy local

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The role of localized energy dissipation

Variance of the local energy

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