Embrittlement overview

Chemical breakdown usually involves oxidative chain reactions that cause embrittlement of semicrystalline polymers and discoloration of poly(vinyl chloride) and polymers with aromatic groups. The reactions are complicated by the presence of transient intermediates and by rates that depend on minute concentrations of molecular defects, impurities and additives. They also depend on several important piiysi-cal factors outlined in this brief overview of polyolefin degradation, two of these factors, the transfer of excitation energy and the transport of products and protectants, play a major role in stabilization processes. 

In this chapter, after giving an overview of the embrittlement of Western pressurized water reactor (PWR) reactor pressure vessel (RPV) beltline materials, together with the characteristics of PWR RPVs, such as their general specification, core region materials and the effects of variables on embrittlement, the surveillance database obtained from US, French and Japanese nuclear power plants (NPPs) and those from other countries is presented based on open literature. The surveillance program of each country is also briefiy described. Trends of surveillance data which will be obtained in the near future are described. The possibility of new data from reconstituted and miniature specimen techniques is described. 

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