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Eliminations to Form Carbon-Oxygen Double Bonds Oxidation Reactions

14 Eliminations to Form Carbon-Oxygen Double Bonds Oxidation Reactions [Pg.380]

Oxidation of a primary alcohol produces an aldehyde. Further oxidation of an aldehyde to produce a carboxylic acid occurs readily. Therefore, if it is desired to stop the reaction at the aldehyde stage, special reagents must be employed. Secondary alcohols are oxidized to ketones. Tertiary alcohols are inert to most oxidizing reagents. [Pg.381]

CHAPTER 10 SYNTHETIC USES OF SUBSTITUTION AND ELIMINATION REACTIONS [Pg.382]

Na2Cr207, KiCijOy, or Cr03 in H2SO4 and H 0 Used for simple alcohols that can tolerate acidic conditions good for oxidizing secondary alcohols to ketones can be used to oxidize primary alcohols to carboxylic acids. [Pg.383]

Cr03 2 Chromium trioxide-pyridine complex is used when nonacidic conditions are needed good for converting secondary alcohols to ketones or primary alcohols to aldehydes without overoxidation. [Pg.383]


ELIMINATIONS TO FORM CARBON-OXYGEN DOUBLE BONDS OXIDATION REACTIONS... [Pg.381]




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Bond-forming

Bonding oxidation reactions

Bonds carbon-oxygen double bond

Bonds to Carbon

Bonds to Oxygen

Carbon elimination

Carbon forms

Carbon oxidation reaction

Carbon oxidative reactions

Carbon oxygenated

Carbon oxygenation

Carbon-oxygen bond

Carbon-oxygen bond forming reactions

Double Elimination reaction

Double bonds oxidation

Double bonds, reactions

Double carbonate

Double oxidative reaction

Double oxides

Elimination oxide

Oxidation elimination

Oxidative -elimination

Oxides bonding

Oxygen Bond-Forming Reactions

Oxygen bonds formed

Oxygen eliminations

Oxygen forms

Reaction bond-forming

Reaction double

Reactions to double bonds

To oxygen

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