Elements history

Chemical elements—History. 2. Matter—Constitution—History. 

Extractive separation of metals is usually based on complex formation with inorganic and organic ligands. Therefore the use of the ideas, approaches, and methods of coordination chemistry has always been a most fruitful approach to the extraction of the elements. History shows that many problems of selectivity of separation or enhanced isolation have been successively solved by the rational application of coordination chemistry, e.g., the concept of hard and soft acids and bases. The efficiency of extraction depends on, inter alia, the ratio of charge and coordination number of metal ion. Study of this effect permitted the development of ways to improve separation due to changes in hydration of the species to be extracted. 

Even if all of the elements described so far have been present within a sedimentary basin an accumulation will not necessarily be encountered. One of the crucial questions in prospect evaluation is about the timing of events. The deformation of strata into a suitable trap has to precede the maturation and migration of petroleum. The reservoir seal must have been intact throughout geologic time. If a leak occurred sometime in the past, the exploration well will only encounter small amounts of residual hydrocarbons. Conversely, a seal such as a fault may have developed early on in the field s history and prevented the migration of hydrocarbons into the structure. 

In these cases what is usually measured is not the time of the original formation of the rocks, but the time at which the parent and daughter elements were last separated. That is, if the rocks were remelted at some point in their history in a manner that removed the daughter elements, this would be the age measured. For the measurements this is especially important. The daughter is a gas and thus could escape at any time when it was not sealed in. The decay sequences of Th, and all have gaseous members in their decay chains (see Tables 1 and 2), but the final members are solids. 

Roofs are a basic element of shelter from inclement weather. Natural or hewn caves, including those of snow or ice, ate early evidence of human endeavors for protection from the cold, wind, rain, and sun. Nomadic people, before the benefits of agriculture had been discovered and housing schemes developed, depended on the availabiUty of natural materials to constmct shelters. Portable shelters, eg, tents, probably appeared early in history. Later, more permanent stmctures were developed from stone and brick. SaUent features depended strongly on the avadabihty of natural materials. The Babylonians used mud to form bricks and tiles that could be bonded with mortars or natural bitumen. Ancient buildings in Egypt were characterized by massive walls of stone and closely spaced columns that carried stone lintels to support a flat roof, often made of stone slabs. 

The elemental composition of the fish otoliths is a potential source of the useful information to recreate environment history of the individual fish in some of the species. In-depth study of the chemical composition of the otolith center (formed eaidy in fish life) and otolith edge (formed later in fish life) ensures chronological and environmental information stored in the otoliths [1]. This infoiTnation may be achieved by X-ray electron probe microanalysis (EPMA). EPMA is the analytical method to determine the elemental composition of different otolith s parts, their sizes varying from ten up to some tens of microns. 

Maintenance and production records, along with the used lean and rich glycol analyses, can be very helpful to the troubleshooter. A history of filter element, carbon, tower packing, and firetube changeouts can sometimes be very revealing. The frequency of pump repairs and chemical cleaning jobs is also beneficial. With this type of knowledge, the troubleshooter can quickly eliminate and prevent costly problems. 

Suits and Bueche conclude their case-histories with a superb analysis of the sources, tactics and uses of applied research, and make the comment The case histories just summarised show, first of all, the futility of trying to label various elements of the research and development process as basic , applied or development . Given almost any definition of these terms, one can find variations or exceptions among the examples. ... 

Chemicals are composed of atoms, discrete particles of matter incapable of further subdivision in the course of a chemical reaction. They are the smallest units of an element. Atoms of the same element are identical and equal in weight. All specimens of gold have the same melting point, the same density, and the same resistance to attack by mineral acids. Similarly, all samples of iron of the same history will have the same magnetism. Atoms of different elements have different properties and differ in weight. 

It is clear that European civil aircraft manufacturers adopted adhesive bonding for major structural elements much more rapidly than their American counterparts, but it is difficult to determine exactly why. Certainly a number of contributing factors are obvious. One was a history of success in incorporating adhesively bonded structure in military aircraft such as the Mosquito. Although the Mosquito was the most unusual and extreme example of adhesively bonded structure, other European wartime aircraft contained bonded structure as well. American military craft of the time were almost exclusively riveted aluminum structure. 

For describing structural loading functions needed for design analysis, the use of overdriven detonation data representing the net overpressure (run-up side less protected side overpressure) on the arrester element and supporting structure is preferable to data representing only the run-up side, side-on overpressure. However, the run-up side transient history of side-on overpressure for overdriven detonations should provide a conservative estimate for design purposes (see Chapter 6). 

The elements are obtainable in a state of very high purity but some of their physical properties are nonetheless variable because of their dependence on mechanical history. Their colours (Cu reddish, Ag white and Au yellow) and sheen are so characteristic that the names of the metals are used to describe them. Gold can also be obtained in red, blue and violet colloidal forms by the addition of vtirious reducing agents to very dilute aqueous solutions of gold(III) chloride. A remarkably stable example is the Purple of Cassius , obtained by using SnCla as reductant, which not only provides a sensitive test for Au but is also used to colour glass and ceramics. Colloidal silver and copper are also obtainable but are less stable. 

CdO is produced from the elements and, depending on its thermal history, may be greenish-yellow, brown, red or nearly black. This is partly due to particle size but more importantly, as with ZnO, is a result of lattice defects — this time in an NaCl lattice. It is more basic than ZnO, dissolving readily in acids but hardly at all in alkalis. White Cd(OH)2 is precipitated from... 

In 1934 Fermi decided to bombard uranium with neutrons in an attempt to produce transuranic elements, that is, elements beyond uranium, which is number 92 in the periodic table. He thought for a while that he had succeeded, since unstable atoms were produced that did not seem to correspond to any known radioactive isotope. I le was wrong in this conjecture, but the research itself would eventually turn out to be of momentous importance both for physics and for world history, and worthy of the 1938 Nobel Pri2e in Physics. 

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