Electron redistribution schematic

Electronic properties, nanostructured materials, 4-5 Electron redistribution phenomenon of d orbitals, 116-117 schematic, 117... 

Using the results discussed above one may try to draw a schematic picture of the effect of substituents on nitrogen inversion barriers in terms of the electronic redistributions they are producing. This picture and the discussed electronic factors should be considered as ad hoc reasoning based on the effects described above, rather than as a real physical explanation. 

Fig. 14. Schematic representation of electron redistribution from metal to dy ...

Fig. 1.2. Schematic illustration of electronic (a) and vibrational (b) predissociation. In the first case, the molecule undergoes a radiationless transition (rt) from the binding to the repulsive state and subsequently decays. In the second case, the photon creates a quasi-bound state in the potential well which decays either by tunneling (tn) or by internal energy redistribution (IVR).

Figure 8.4. Schematic of the C2H4-Ag interactions by jr-complexation, showing (A) donation of JT-electrons of efhylene to the 5s orbital of Ag, (B) backdonation of electrons from the 4dyz orbitals of Ag to the antibonding p orbitais of ethyiene, and (C) eiectron redistribution. (C) depicts the possibie eiectron redistribution from the 4dz2 orbitais to the 4dyz orbitals (Chen and Yang, 1996, with permission).

Schematic plots of current versus time for CulCul graphite. The solid lines indicate the oscillographic trace obtained experimentally. The dashed curves represent the current due to double layer charging and to electron hole redistribution.

Explaining the stability of a chemical bond requires us to consider, from a quantum mechanical point of view, the redistribution of electron density from the nudei to the intemudear region. The redistribution of electron density that occurs in the formation of a bond between two H atoms is illustrated schematically in Figure 11-3(a), which compares the electron density of the H2 molecule with that of the nonbonded H atoms. 

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