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Electron homogeneous distribution

For many years, research efforts in materials chemistry have focused on the development of new methods for materials synthesis. Traditional areas of interest have included the synthesis of catalytic, electronic, and refractory materials via aqueous methods (sol-gel and impregnation) and high-temperature reactions [1-3]. More recent strategies have focused on the synthesis of materials with tailored properties and structures, including well-defined pores, homogeneously distributed elements, isolated catalytic sites, comphcated stoichiometries, inorganic/organic hybrids, and nanoparticles [4-13]. A feature... [Pg.70]

Electrochemical template-controlled sjmthesis of metallic nanoparticles consists of two steps (i) preparation of template and (ii) electrochemical reduction of metals. The template is prepared as a nano structured insulating mono-layer with homogeneously distributed planar molecules. This is a crucial step in the whole technology. The insulating monolayer has to possess perfect insulating properties while the template has to provide electron transfer between electrode and solution. Probably, the mixed nano-structured monolayer consisting of alkylthiol with cavities which are stabilized by the spreader-bar approach [19] is the only known system which meets these requirements. [Pg.321]

In a nonattaching gas electron, thermalization occurs via vibrational, rotational, and elastic collisions. In attaching media, competitive scavenging occurs, sometimes accompanied by attachment-detachment equilibrium. In the gas phase, thermalization time is more significant than thermalization distance because of relatively large travel distances, thermalized electrons can be assumed to be homogeneously distributed. The experiments we review can be classified into four categories (1) microwave methods, (2) use of probes, (3) transient conductivity, and (4) recombination luminescence. Further microwave methods can be subdivided into four types (1) cross modulation, (2) resonance frequency shift, (3) absorption, and (4) cavity technique for collision frequency. [Pg.250]

Scanning electron micrography indicates that zeolite crystals are homogeneously distributed in the composites. Micrographs show the characteristic aggregates of octahedral crystals of zeolite X from methods A and C and the cubic crystals of zeolite A from method B. [Pg.391]

The quantum tricks to realize high Tc superconductors are based on the generic feature of the electronic structure of the superlattices the presence of different subbands where the charge density associated with each subband is non homogenously distributed in the real space and single electron interband hopping is forbidden by symmetry. [Pg.28]

The route of catalyst deactivation via a cyclic metal impregnation and deactivation method has produced significant improvements in approaching realistic vanadium and nickel profiles over the catalyst particles. From electron microprobe analyses of Ni and V loaded catalyst it has been established that after pore volume saturation, Ni and V are rather homogeneously distributed over the catalyst. [Pg.338]

Fig. 30. Change of potential when an electron passes through a double layer with homogeneously distributed electric charge. Fig. 30. Change of potential when an electron passes through a double layer with homogeneously distributed electric charge.
Only E3 is new and rather unusual. It describes the overpopulation of ion pairs [D+ A-], produced by electron transfer in closely situated products of ion recombination in the bulk, excited before their separation. Since the density of the correlated pairs is enhanced through bulk recombination, the ionization becomes faster than at the entirely homogeneous distribution of the reactants. The terms involving S3 account for this effect. However, unlike other kernels, E3 vanishes in the lowest-order approximation with respect to 7o- Therefore,... [Pg.292]

In a simplified, often used, picture of homogeneously distributed singlets, their concentration, S, under steady-state electron-hole recombination conditions, can be expressed by a simple equation... [Pg.345]


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See also in sourсe #XX -- [ Pg.29 ]




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