Electron exchange kinetics

As an extension of the intermolecular self-exchange described above, the solvent-induced intramolecular electron exchange kinetics in radical anions of 1,3-dinitrobenzene [47] and benzene 1,3-dicarbaldehyde [48] have been studied by several authors (Freed and Fraenkel, 1964 Grampp et al., 1989, 1990b Shohoji et al, 1987). The advantage of [47] and [48] is their structural simplicity and their high stability, which allows measurements even in protic... 

Mechanistic Studies of Electron Exchange Kinetics Using Ab Initio Electronic Structure Techniques... 

This brings us to the rear support-film interface. What sort of barrier exists at this junction Are the electron exchange kinetics voltage-dependent at this interface The effect of changing the work function of the substrate on the current-voltage curves (in the dark and under illumination) has been investigated for Ti02 nanocrystalline films [344]. The onset potential for the photocurrent is found to be the... 

Experimentally determined electron exchange kinetics between these mediators and laccase are shown in Figure 9.8 [73]. When AEet.c is small, the bimolecular rate constant is on the order of 100-200 M s . As A et,c increases to near 0.4 V, the rate constant increases to 100,000M s and plateaus. 

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