Electromagnetic radiation particle properties

Light has a dual character - it may be described either as a wave motion or as a stream of moving particles. Since light is a form of electromagnetic radiation, its properties, as with all forms of electromagnetic radiation, are... 

In words, an electron beam should exhibit wave properties for example, like light, it should produce a diffraction pattern. This prediction has been verified by numerous experiments. Fig. 6.12. Thus, like electromagnetic radiations, particles of matter exhibit wave properties and particle properties. The electron microscope, now a common laboratory tool (Fig. 26.6, page 562), is an application of the de Broglie concept. 

Electromagnetic radiation of which visible light is but one example has the properties of both particles and waves The particles are called photons, and each possesses an amount of energy referred to as a quantum In 1900 the German physicist Max Planck proposed that the energy of a photon (E) is directly proportional to its frequency (v)... 

In the early development of the atomic model scientists initially thought that, they could define the sub-atomic particles by the laws of classical physics—that is, they were tiny bits of matter. However, they later discovered that this particle view of the atom could not explain many of the observations that scientists were making. About this time, a model (the quantum mechanical model) that attributed the properties of both matter and waves to particles began to gain favor. This model described the behavior of electrons in terms of waves (electromagnetic radiation). 

Electromagnetic radiation can be absorbed or emitted. The absorption of ultraviolet radiation by our skin may cause sunburn. When we cook food in a microwave oven, the absorption of microwave radiation by the water in the food causes the water molecules to vibrate, generating heat that cooks the food. However, when electromagnetic radiation is absorbed or emitted by matter, it behaves more like a stream of particles than as a wave motion. These particles are called photons and so electromagnetic radiation can be considered both as a stream of photons and as waves with characteristic properties, such as wavelength (1) and frequency (/). Therefore we say that electromagnetic radiation has a dual nature wave motion and streams of photons. 

In diffuse reflection spectroscopy, the spectrometer beam is reflected from, scattered by, or transmitted through the sample, whereas the diffusely scattered light is reflected back and directed to the detector. The other part of the electromagnetic radiation is absorbed or scattered by the sample [124,125]. Changes in band shapes or intensity as well as signal shifts can be affected by morphological and physicochemical properties of the sample or combinations thereof (e.g., chemical absorptions, particle size, refractive index, surface area, crystallinity, porosity, pore size, hardness, and packing density [126]). Therefore, NIR diffuse reflection spectra can be interpreted in dependence of various physical parameters [127]. 

A significant change in the theoretical treatment of atomic structure occurred in 1924 when Louis de Broglie proposed that an electron and other atomic particles simultaneously possess both wave and particle characteristics and that an atomic particle, such as an electron, has a wavelength X = h/p = h/mv. Shortly thereafter, C.J, Davisson and L.H. Germer showed experimentally the validity of this postulate. Dc Broglie s assumption that wave characteristics are inherent in every atomic particle was quickly followed by the development of quantum mechanics, in its most simple form, quantum mechanics introduces the physical laws associated with the wave properties of electromagnetic radiation into the physical description of a system of atomic particles. By means of quantum mechanics a much more satisfactory explanation of atomic structure can be developed. 

Although the nucleus is normally found in its lowest energy state, it may be produced as the result of a nuclear reaction, or tlirougli radioactivity in a number of excited states whose detailed properties may differ quite markedly from the lowest state, if formed in an excited state, it will decay, normally by the emission of electromagnetic radiation (gamma rays) lo the lowest state, or by the emission of particles to another nucleus. 

A full explanation of the properties of light requires both the wave theory of electromagnetic radiation and the quantum theory. Most photochemical processes are best understood in terms of the quantum theory, which says that light is made up of discrete particles called quanta or photons. Each quantum carries an amount of energy, S, determined by the wavelength of the light, A. Equation 13.1, in which h is Planck s constant and c is the speed of light in a vacuum,... 

It turns out that electromagnetic waves exhibit properties of both waves and particles, or equally valid, electromagnetic waves are neither waves nor particles. This fundamental paradox is at the heart of quantum theory. You can perform experiments that unequivocally demonstrate light is definitely a wave. You can also perform experiments that unequivocally demonstrate light is definitely a particle. Nonetheless, there is one important relationship that allows the energy of electromagnetic radiation to be calculated if the frequency or wavelength is known ... 

Furthermore, multiple ionization, which has been postulated as being able to bring about displacements of interior atoms (30), might be extremely effective in leading to surface migrations and thermal patches, in which case surface properties could be more sensitive to electromagnetic radiation than to particle radiation. it was hoped that the present studies would shed some light on what actually happens. 

Refractive index — A fundamental physical property of materials through which light can travel. It is usually indicated by the symbol n, and it is defined as n = c/cQ, where c0 is the speed of light in vacuum and c corresponds to the speed at which the crests of electromagnetic radiation corresponding to a specific frequency propagate in a material [i,ii], A more rigorous definition for the refractive index of a dense and isotropic material composed of a unique kind of particles (atoms or... 

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